Concentrations of dissolved copper in the eastern Atlantic Ocean 23°N to 47°N

Abstract

CONSIDERABLE uncertainties still exist as to the abundances of most of the trace metals in seawater, including some of the more intensively investigated elements. Recent analyses of copper in surface waters south of New Zealand¹ and in waters from various depths over the East Pacific Rise² have given values of 0.06–0.40 µg l⁻¹, and a similar range has been found by M. J. McCartney (personal communication) for samples from the Mediterranean Sea and the northeastern Atlantic Ocean. A geometric mean concentration of 0.26 µg l⁻¹ has been reported for samples collected off the shelf west of Scotland³. These values are either below or at the lower end of the ranges reported for seawater by other workers. For example, extensive measurements⁴ of dissolved copper in surface waters have given average concentrations for various near-shore and open ocean regions which vary between 0.3 and 1.7 µg 1⁻¹, with a mean of 0.8 µg l⁻¹, and a number of other recent investigations^5–8 of North Atlantic Ocean waters also support an abundance value of ∼ 1 µg 1⁻¹. These contrasting findings may reflect real environmental variability but the alternative explanation that such variations are, at least in part, attributable to analytical problems, and especially to contamination, must also be considered. This communication reports values for dissolved copper in samples taken from the eastern Atlantic Ocean in October and November, 1975, which support findings of concentrations of ∼ 0.2 µg l⁻¹. The results of measurements on these samples of the organically associated copper are summarised.