Opto-acoustic spectroscopy of products of continuous photolysis of nitromethane

Abstract

THE photolysis of nitromethane has been carried out with both continuous (see ref. 1) and flash sources (see ref. 2), but for continuous photolysis no concurrent spectroscopy has been reported. This is in general true of most photolysis experiments, since the steady-state concentration of intermediates produced by continuous sources is usually insufficient to record spectra without depending on some matrix isolation procedure. We report here on gas phase continuous wave photolysis experiments using opto-acoustic detection of the energy absorbed by intermediates from a continuous wave (CW) tunable dye laser³. This allowed the detection of intermediate concentrations of ∼ 10¹³ mol cm⁻³. Opto-acoustic detection was discovered by Bell⁴ nearly a century ago, but was recently revived as a means of monitoring low concentrations of pollutant molecules^5,6. In our experiments the intermediates act as the ‘pollutant’ molecules to be detected.