Abstract
IN the course of systematic studies1 of the synthesis and properties of clathrate inclusion compounds we found that compound II, formed by adding a methyl group to the clathrating compound I, also exhibits clathrating properties. It was evident, however, both from preliminary crystallographic measurements and from their very different selectivities towards guest molecules that the cavities in the host structure of I and II differ markedly2. We present here details of the cavities in II and compare them with those reported earlier for I (ref. 3).
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Hardy, A. D. U., MacNicol, D. D., and Wilson, D. R., Chem. Commun., 783–784 (1974).
Hardy, A. D. U., McKendrick, J. J., and MacNicol, D. D., Chem. Commun., 972–973 (1974).
MacNicol, D. D., and Wilson, F. B., Chem. Commun., 786–787 (1971).
International Tables for X-ray Crystallography, 1 (edit. by Macgillavry, C. H., and Rieck, G. D.; gen. ed. Lonsdale, K.), 253 (Kynoch, Birmingham, 1965).
Bhatnagar, V. M., Clathrate Compounds, ch. 4 (Chemical Publishing, New York, 1970).
Emert, J., and Breslow, R., J. Am. chem. Soc., 97, 670–672 (1975).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
MACNICOL, D., HARDY, A. & MCKENDRICK, J. Alteration of cavity geometry by structural modification of clathrate host molecules. Nature 256, 343–344 (1975). https://doi.org/10.1038/256343a0
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1038/256343a0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.