Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

17α(H) Hopane identified in Oil Shale of the Green River Formation (Eocene) by Carbon-13 NMR

Abstract

THE occurrence of steroid and terpenoid saturated hydrocarbons in organic sediments is well known and their geological significance has been established1–4. These steranes and terpanes represent the complete reduction of naturally occurring steroids or terpenoids to relatively stable fossil molecules which preserve intact the complete molecular skeleton and stereochemistry of their precursors. Steranes and terpanes, together with other “biological markers”, provided convincing proof for the biological origin of petroleums, oil shales, and other organic matter in sediments all over the world.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Meinschein, W. G., Space Sci. Rev., 2, 653 (1963).

    Article  ADS  CAS  Google Scholar 

  2. Bradley, W. H., Geol. Soc. Amer. Bull., 77, 1333 (1966).

    Article  ADS  Google Scholar 

  3. Henderson, W., Wollrab, V., and Eglinton, G., in Advances in Organic Geochemistry (edit. by Schenk, P. A., and Havenaar, I.), 181 (Pergamon Press, New York, 1968).

    Google Scholar 

  4. Anderson, P. C., Gardner, P. M., Whitehead, E. V., Anders, D. E., and Robinson, W. E., Geochim. Cosmochim. Acta, 33, 1304 (1969).

    Article  ADS  CAS  Google Scholar 

  5. Gelpi, E., Wszolek, P. C., Yang, E., and Burlingame, A. L., Anal. Chem., 43, 864 (1971).

    Article  CAS  Google Scholar 

  6. Henderson, W., Wollrab, V., and Eglinton, G., Chem. Commun., 710 (1968).

  7. Hills, I. R., and Whitehead, E. V., Nature, 209, 977 (1966).

    Article  ADS  CAS  Google Scholar 

  8. Whitehead, E. V., Chem. Ind., 1116 (1971).

  9. Whitehead, E. V., Inter. Symp. Hydrogeochemistry and Biogeochemistry, Tokyo, Abst. Pap., Sci. Counc. Jap.-Inter. Ass. Geochem. Cosmochem., 80 (Tokyo, 1970).

  10. Freeman, R., Hill, H. D. W., and Kaptein, R., J. Magn. Res., 7, 327 (1972).

    ADS  CAS  Google Scholar 

  11. Birdsall, B., Birdsall, N. J. M., and Feeney, J., Chem. Commun., 316 (1972).

  12. Packler, K. G. R., J. Magn. Res., 7, 442 (1972).

    ADS  Google Scholar 

  13. Balogh, B., Wilson, D. M., and Burlingame, A. L., Nature, 233, 261 (1971).

    Article  ADS  CAS  Google Scholar 

  14. Dalling, D. K., and Grant, D. M., J. Amer. Chem. Soc., 94, 5318 (1972).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

BALOGH, B., WILSON, D., CHRISTIANSEN, P. et al. 17α(H) Hopane identified in Oil Shale of the Green River Formation (Eocene) by Carbon-13 NMR. Nature 242, 603–605 (1973). https://doi.org/10.1038/242603a0

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1038/242603a0

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing