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Structure of Tin(II) “Hydroxide” and Lead(II) “Hydroxide”

Abstract

Donaldson and Moser1 have shown that there is only one stable solid tin(II) hydroxide, a unique crystalline phase quite distinct from other tin(II) oxides, which can be described as a hydrous oxide or oxy-hydroxide. The formula of the finely divided material was determined analytically as 5SnO.2H2O, but analytical results on a fine powder of large surface area cannot distinguish between this formula and the alternative 3SnO.H2O, which differs by only one molecule of water per fifteen formula units of tin(II) oxide.

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References

  1. 1

    Donaldson, J. D., and Moser, W., J. Chem. Soc., 835 (1961).

  2. 2

    Donaldson, J. D., Acta Cryst., 14, 65 (1964).

    Article  Google Scholar 

  3. 3

    Cotton, F. A., Quart. Rev., 20, 389 (1966).

    CAS  Article  Google Scholar 

  4. 4

    Wells, A. F., Structural Inorganic Chemistry, third ed. (Oxford University Press, 1962).

    Google Scholar 

  5. 5

    Tobias, R. S., Acta Chem. Scand., 12, 198 (1958).

    CAS  Article  Google Scholar 

  6. 6

    Todd, G., and Parry, E., Nature, 202, 386 (1964).

    ADS  CAS  Article  Google Scholar 

  7. 7

    Clark, G. L., and Tyler, W. P., J. Amer. Chem. Soc., 61, 58 (1939).

    CAS  Article  Google Scholar 

  8. 8

    Hentz, F. C., and Tyree, S. Y., Inorg. Chem., 3, 814 (1964).

    Article  Google Scholar 

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HOWIE, R., MOSER, W. Structure of Tin(II) “Hydroxide” and Lead(II) “Hydroxide”. Nature 219, 372–373 (1968). https://doi.org/10.1038/219372a0

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