Abstract
WE present here the results of an electron spin resonance investigation of the free radicals formed from diethyl-hydroxylamine, dioctylhydroxylamine and N-hydroxypyrrolidine. Dioctylhydroxylamine was prepared by the method of Harris and Olcott1. Diethylhydroxylamine was obtained from Pennsalt Chemicals (85 per cent and 100 per cent) and from K and K Laboratories (85 per cent). N-Hydroxypyrrolidine was prepared by the method Wolfenstein2 used for N-hydroxypiperidne and by the method described by Blout3.
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References
Harris, L. A., and Olcott, H. S., J. Amer. Oil Chem. Soc., 43, 11 (1966).
Wolfenstein, R., Chem. Ber., 25, 2777 (1892).
Blout, E. R., Cohen, S. G., and Green, M., US Patent 2,843,481, July 15, 1958.
Coppinger, G. M., and Swalen, J. D., J. Amer. Chem. Soc., 83, 4900 (1961).
Chapelet-Letourneurx, G., Lemaire, H., and Rassat, A., Bull. Soc. Chim., 3283 (1965).
Adams, J. Q., Nicksic, S. W., and Thomas, J. R., J. Chem. Phys., 45, 654 (1966).
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WEIL, J., WINDLE, J. Electron Spin Resonance Study of Nitroxide Radicals from Diethylhydroxylamine, Dioctylhydroxylamine and N-Hydroxypyrrolidine. Nature 217, 842–843 (1968). https://doi.org/10.1038/217842b0
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DOI: https://doi.org/10.1038/217842b0
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