Abstract
THE growth of single crystals by controlled diffusion in gels at near ambient temperatures offers intriguing advantages for substances which are sparingly soluble in the gel medium or which dissociate at the high temperatures so frequently employed for crystal growth1, or both. The gel diffusion growth method has been described as most applicable to materials with solubilities in aqueous solutions in the order of 10−1 to 10−2 weight per cent at ambient temperatures2. We report the successful application of the gel growth method to substances, the solubilities of which range from 10−5 to 10−7 weight per cent, thus enhancing its use for preparing single crystals of quite low solubility substances.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
DiPietro, M. A., O'Connor, J. J., and Rubin, B., Phys. Sci. Res. Pap. 227, AFCRL 66–321 (Office Aerospace Research, Bedford, Mass., 1966).
Torgesen, J. L., and Sober, A. J., NBS Tech. Note 260, 1964, issued 1965 (US Dept. of Commerce, National Bureau of Standards, Washington, D.C., 1965).
O'Connor, J. J., DiPietro, M. A., Armington, A. F., and Rubin, B., Nature, 212, 68 (1966).
Mitchell, J. W., in Progress in Semiconductors (edit. by Gibson, A. F.), 3 (J. Wiley, 1958).
Mees, K., in The Theory of the Photographic Process (Macmillan Co., 1959).
US Gov. R.D. Rep., 40 (2), 75 (1965).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
BLANK, Z., SPEYER, D., BRENNER, W. et al. Growth of Single Crystals of Silver Halides in Silica Gels at Near Ambient Temperatures. Nature 216, 1103–1104 (1967). https://doi.org/10.1038/2161103a0
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1038/2161103a0
This article is cited by
-
Growth and characterization of copper zinc hydrogen phosphate single crystals and study of its thermal, optical, dielectric, and NLO properties
Journal of Materials Science: Materials in Electronics (2021)
-
Growth and thermal kinetics of pure and cadmium doped barium phosphate single crystal
Journal of Thermal Analysis and Calorimetry (2011)
-
Growth of Crystals in Silica Gel using a Co-solute
Nature (1968)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.