Abstract
ALTHOUGH calcite is the most stable form of calcium carbonate under Earth-surface conditions1, aragoniite is the form precipitated from aqueous solutions under a wide range of conditions. As was observed by Wray and Daniels2, for example, aragonite is precipitated at temperatures higher than 40° C, whereas at lower temperatures only calcite is formed. In the presence of Mg++ ions, however, for example in sea water, the formation of aragonite has been observed at temperatures lower than 40° C (refs. 3–8).
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References
Simmons, G., and Bell, P., Science, 139, 1197 (1963).
Wray, J. L., and Daniels, F., J. Amer. Chem. Soc., 79, 2031 (1957).
Vetter, H., Z. f. Krist., 48, 45 (1911).
Köhler, E., Chemie der Erde, 6, 257 (1931).
Togari, K., and Togari, S., J. Fac. Sci., Hokkaido Univ., Ser. IV, 9, 55 (1955).
Lippmann, F., Fortschr. Mineral., 38, 156 (1960).
Kitano, Y., Bull. Chem. Soc. Japan, 35, 1973 (1962).
Groot, K. de, Nature, 207, 404 (1965).
Cloud, P. E., U.S. Geol. Survey Prof. Paper, 350, 121 (1962).
Friedman, G. M., J. Sed. Petrol, 34, 777 (1964).
Berner, R. A., Amer. J. Sci., 264, 1 (1966).
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DE GROOT, K., DUYVIS, E. Crystal Form of Precipitated Calcium Carbonate as influenced by Adsorbed Magnesium Ions. Nature 212, 183–184 (1966). https://doi.org/10.1038/212183a0
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DOI: https://doi.org/10.1038/212183a0
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