Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Iodine as a Scavenger for Hydrogen Atoms in Irradiated Ethanol

Abstract

As with most organic compounds, one of the principal end-products resulting from the effect of high-energy ionizing radiation on pure ethanol is hydrogen gas. Much interest has been shown recently in the radiolysis of alcohols, and this paper presents data on hydrogen atom yields, which help to distinguish the various possible mechanisms.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Burr, J. G. J., Phys. Chem., 61, 1477 (1957); J. Amer. Chem. Soc., 79, 651 (1957).

    Article  CAS  Google Scholar 

  2. Adams, G. E., Baxendale, J. H., and Sedgwick, R. D., J. Phys. Chem., 63, 854 (1959).

    Article  CAS  Google Scholar 

  3. Awtrey, R. D., and Connick, R. E., J. Amer. Chem. Soc., 73, 1842 (1951).

    Article  CAS  Google Scholar 

  4. DeMaine, P. A. D., J. Chem. Phys., 28, 1002 (1958).

    Article  ADS  CAS  Google Scholar 

  5. Goldschmidt, H. Z., Physik. Chem., 114, 1 (1925).

    Google Scholar 

  6. Walden, Ulich, and Laun, Techniques of Organic Chemistry, 7 (Weissberger: Interscience, 1958).

    Google Scholar 

  7. Meshitsuka, G., and Burton, M., Radiation Res., 8, 285 (1958).

    Article  ADS  CAS  Google Scholar 

  8. Newton, A. S., and McDonell, W. R., J. Amer. Chem. Soc., 78, 4554 (1956).

    Article  CAS  Google Scholar 

  9. Johnsen, R. H., J. Phys. Chem., 65, 2144 (1961).

    Article  CAS  Google Scholar 

  10. Hayon, E., and Weiss, J. J., J. Chem. Soc., 3962 (1961).

  11. Taub, I. A., and Dorfman, L. M., J. Amer. Chem. Soc., 84, 4053 (1962).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

BARKER, N., GREEN, J. Iodine as a Scavenger for Hydrogen Atoms in Irradiated Ethanol. Nature 204, 872–873 (1964). https://doi.org/10.1038/204872a0

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/204872a0

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing