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Iron-deficient Low-temperature Pyrrhotite

Abstract

DURING the past few years considerable attention has been focused on the potential of pyrrhotite as a geothermometer. In 1962 Arnold1 determined experimentally the solvus relationship between hexagonal pyrrhotite and pyrite, thereby demonstrating that the percentage of iron in pyrrhotite along this solvus was temperature dependent, but insensitive to pressure. The potential of this method was then tested on samples from the Highland-Surprise Mine2 and the temperatures obtained from the pyrrhotite geothermometer were found to agree well with those obtained from associated sphalerite using the sphalerite geothermometer3. More recently, Buseck4 and Kullerud et al.5 have attempted to apply the method to monoclinic pyrrhotite–pyrite assemblages by inverting the monoclinic pyrrhotite to hexagonal symmetry by heating.

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References

  1. Arnold, R. G., Econ. Geol., 57, 72 (1962).

    Article  CAS  Google Scholar 

  2. Arnold, R. G., Coleman, R. G., and Fryklund, V. C., Econ. Geol., 57, 1163 (1962).

    Article  CAS  Google Scholar 

  3. Kullerud, G., Norsk Geol. Tidsskr., 32, 61 (1953).

    CAS  Google Scholar 

  4. Buseck, P. R., Ann. Rep. of Director Geophys. Lab., Carnegie Inst., Washington, Year Book 61, 161 (1962).

  5. Kullerud, G., Doe, B. R., Buseck, P. R., and Tröften, P. F., Ann. Rep. Director Geophys. Lab., Carnegie Inst., Washington, Year Book 62, 210 (1963).

  6. Dunham, K. C., Mem. Geol. Surv. Great Britain (H.M.S.O., 1948).

  7. Balitskii, V. S., and Lyubofeyev, V. N., Geochem., 9, 926 (1962).

    Google Scholar 

  8. Dunham, K. C., Dunham, A. C., Hodge, B. L., and Johnson, G. A. L., Quart. J. Geol. Soc. (in the press).

  9. Arnold, R. G., and Reichen, L. E., Amer. Min., 47, 105 (1962).

    CAS  Google Scholar 

  10. Shapiro, L., and Toulmin, M. S., U.S. Geol. Surv. Prof. Pap. 424-B, 328 (1961).

  11. Sawkins, F. J., Econ. Geol. (in the press).

  12. Eastwood, T., British Regional Geol., Northern England (H.M.S.O., 1953).

    Google Scholar 

  13. Trotter, F. M., and Hollingworth, S. E., Mem. Geol. Surv. England and Wales (H.M.S.O., 1932).

    Google Scholar 

  14. Roedder, E., Econ. Geol., 58, 167 (1963).

    Article  CAS  Google Scholar 

  15. Sourirajan, S., and Kennedy, G. C., Amer. J. Sci., 260, 115 (1962).

    Article  ADS  CAS  Google Scholar 

  16. Krauskopf, K. B., Researches in Geochemistry, 260 (John Wiley and Sons, New York, 1959).

    Google Scholar 

  17. van Gehlen, K., and Kullerud, G., Ann. Rep. Director Geophys. Lab., Carnegie Inst., Washington, Year Book 61, 154 (1962).

  18. Skinner, B. J., Barton, jun. P. B., and Kullerud, G., Econ. Geol., 54, 1040 (1959).

    Article  CAS  Google Scholar 

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SAWKINS, F., DUNHAM, A. & HIRST, D. Iron-deficient Low-temperature Pyrrhotite. Nature 204, 175–176 (1964). https://doi.org/10.1038/204175a0

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