Abstract
THE deleterious effects of adsorptive activity in supporting media for gas chromatography are well known; broad, long-tailed peaks are obtained, making area measurements in quantitative work more difficult, and obscuring small peaks due to impurities following a major peak. In so far as adsorptive activity may be due to metallic impurities, some amelioration is commonly effected by acid or alkali washing. However, the surface even of pure silica possesses active adsorption sites, presumably due to free OH groups, and several authors have indicated that adsorption due to this cause can be greatly reduced by treatment of the support with certain reactive silicon compounds.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Kwantes, A., and Rijnders, G. W. A., Gas Chromatography, edit. by Desty, D. H., 125 (Butterworths, London, 1958).
Horning, E. C., Moscatelli, E. A., and Sweely, C. C., Chem. and Indust., 25, 751 (1958).
Crowe, P. F., and Hornstein, I., Anal. Chem., 33, 310 (1961).
Akshinshaya, N. V., et al., Zhuv. fiz. Khim., 36, 1121 (1962).
Kiselev, A. V., et al., Zhuv. fiz. Khim., 35, 1889 (1961).
Bohemen, J., Langer, S. H., Perrett, R. H., and Purnell, J. H., J. Chem. Soc., 2444 (1960).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
ATKINSON, E., TUEY, G. In Situ Treatment of Kieselguhr for Gas Chromatography. Nature 199, 482–483 (1963). https://doi.org/10.1038/199482a0
Issue Date:
DOI: https://doi.org/10.1038/199482a0
This article is cited by
-
Gas-liquid chromatography of drugs
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science (1970)
-
The use of gas-liquid chromatography for the analysis of gibberellins and related compounds
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science (1969)
-
Graschromatographie ringhomologer Cyclanone
Fresenius' Zeitschrift für analytische Chemie (1966)
-
Rejuvenation of Gas Liquid Chromatography Columns in situ
Nature (1963)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.