Abstract
THE rate of recombination of chlorine atoms has been investigated using a flow system. The atoms were produced in a microwave discharge, and the atom decay followed by means of a movable thermocouple probe at which recombination occurred. The reaction tube of 4-cm internal diameter was poisoned with boric oxide. Runs using chlorine only, and chlorine/argon mixtures, were carried out. Linear flow speeds in the range 30–250 cm/sec, and total pressures (measured with a sloping oil manometer) of 0.24–3 mm mercury were used.
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References
- 1
Ogryzlo, E. A., Canad. J. Chem., 39, 2556 (1961).
- 2
Andrussov, L., Z. Elektrochemie, 54, 566 (1950).
Author information
Affiliations
Inorganic Chemistry Laboratory, University of Oxford
- J. W. LINNETT
- & M. H. BOOTH
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Further reading
-
On the kinetics of the chlorination of titanium dioxide in the presence of solid carbon
Metallurgical Transactions B (1980)
-
Recombination of Chlorine Atoms
Nature (1964)
-
Recombinations of Chlorine Atoms
Nature (1964)
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