Letter | Published:

Preparation of Lower Oxide of Sulphur

Naturevolume 193pages773774 (1962) | Download Citation



RECENT work on the lower oxide of sulphur1,2 has established that disulphur monoxide (S2O) or its polymeric form is produced when sulphur is burnt in oxygen under reduced pressure. It has now been shown that it is possible to make use of an oxide of a heavy metal as a source of limited supply of oxygen to prepare the disulphur monoxide. For example, when a mixture of finely powdered cupric oxide and sulphur (1 : 5 by weight) is heated under vacuum in a glass tube gaseous products are evolved. which, on cooling in a trap surrounded by liquid air, will give an orange-red condensate (S2O)x. This condensate also gives off sulphur dioxide in stages as the temperature is raised, finally leaving a residue of elemental sulphur. Copper sulphide and excess of sulphur are left behind in the reaction tube.

Access optionsAccess options

Rent or Buy article

Get time limited or full article access on ReadCube.


All prices are NET prices.


  1. 1

    Murthy, A. R. Vasudeva, Proc. Ind. Acad. Sci., 36, 388, 425 (1952).

  2. 2

    Meschie, J., and Myers, R. J., J. Mol. Spect., 3, 405 (1959).

  3. 3

    Ondrejcin, R. S., U.S. Atomic Energy Comm., D-P-497 (1960).

Download references

Author information


  1. Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore, 12



  1. Search for A. R. VASUDEVA MURTHY in:

About this article

Publication history

Issue Date




By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.