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Structure of Molybdenum Sesquisulphide

Abstract

THE existence of molybdenum sesquisulphide, Mo2S3, as a distinct phase has been in doubt for a considerable time. It was only in 1955 that McCabe1 convincingly demonstrated the existence of the phase and obtained its X-ray powder pattern. An attempt to index the powder pattern has been made by Stubbles and Richardson2; they tentatively propose a tetragonal unit cell with c = 10.9 Å.; c/a = 1.27.

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References

  1. McCabe, C. L., J. Metals, 7, 61 (1955).

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  2. Stubbles, J. R., and Richardson, F. D., Trans. Farad. Soc., 56, 1460 (1960).

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  3. Dickinson, R. G., and Pauling, L., J. Amer. Chem. Soc., 45, 1465 (1923). Jellinek, F., Brauer, G., and Müller, H., Nature, 185, 376 (1960).

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JELLINEK, F. Structure of Molybdenum Sesquisulphide. Nature 192, 1065–1066 (1961). https://doi.org/10.1038/1921065a0

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