Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Crystal and Molecular Structure of Diphenyl

An Erratum to this article was published on 16 December 1961

Abstract

X-RAY diffraction studies of crystalline diphenyl have been described by a number of authors1–4 but the bond-distances and bond-angles have not been determined as accurately as in other aromatic compounds recently reported5. A detailed X-ray investigation of this structure has now been completed, and in view of the relevance of accurate structural information to modern valency theory, some results of this analysis are reported here.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Dhar, J., Indian J. Phys., 7, 43 (1932).

    CAS  Google Scholar 

  2. Dhar, J., Proc. Nat. Inst. Sci. India, 15, 11 (1949).

    CAS  Google Scholar 

  3. Kitiagorodsky, A. I., Acta Physiochim. U.R.S.S., 2l, 575 (1946).

    Google Scholar 

  4. Hargreaves, A., and Hasan Rizvi, S., Proc. Chem. Soc., 122 (1961).

  5. For example, Cruickshank, D. W. J., Acta Cryst., 9, 915 (1956).

    Article  CAS  Google Scholar 

  6. International Tables for X-Ray Crystallography, 2, 330.

  7. Allmeningen, A., and Bastiansen, O., Det Kgl. Norske Videnskabers Selskabs Skrifter, No. 4 (1958).

  8. Sparks, R. A., Ph.D. thesis, University of California at Los Angeles (1958).

  9. Cramer, H., The Elements of Probability Theory (John Wiley and Sons, Inc., New York, 1955).

    Google Scholar 

  10. Cruickshank, D. W. J., Acta Cryst., 9, 754, 757 (1956).

    Article  CAS  Google Scholar 

  11. For example, Goodwin, T. H., J. Chem. Soc., 4851 (1960).

  12. Mulliken, R. S., Tetrahedron, 6, 68 (1959).

    Article  CAS  Google Scholar 

  13. Dewar, M. J. S., and Schmeising, H. N., Tetrahedron, 5, 105 (1959).

    Article  Google Scholar 

  14. Cruickshank, D. W. J., and Sparks, R. A., Proc. Roy. Soc., A, 258, 270 (1960).

    Article  ADS  CAS  Google Scholar 

  15. Brown, M. G., Trans. Farad. Soc., 55, 694 (1959).

    Article  CAS  Google Scholar 

  16. Coulson, C. A., and Longuet-Higgins, H. C., Proc. Roy. Soc., A, 195, 188 (1948).

    Article  ADS  CAS  Google Scholar 

  17. Mason, R. (private communication).

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

ROBERTSON, G. Crystal and Molecular Structure of Diphenyl. Nature 191, 593–594 (1961). https://doi.org/10.1038/191593a0

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/191593a0

This article is cited by

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing