Abstract
ALTHOUGH several authors, notably Staverman1 and Spiegler2, have applied the methods of the thermodynamics of the steady-state to the treatment of electrodialysis processes, little or no attention has been given to the possible existence of heat fluxes in electrodialysis experiments. Of course, very useful relationships can be obtained between the flow of charge and the flow of matter through an appropriate treatment of an isothermal experiment, but we cannot say that we have described the system unless we consider the possibility of heat flows induced by these transport processes.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Staverman, Trans. Farad. Soc., 48, 176 (1952).
Spiegler, Trans. Farad. Soc., 54, 1408 (1958).
Callen, Phys. Rev., 73, 1349 (1948).
deBethune, J. Electrochem. Soc., 107, 829 (1960).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
SHAFFER, L. Thermo-electric Phenomena in Electrodialysis Systems. Nature 191, 591–592 (1961). https://doi.org/10.1038/191591b0
Issue Date:
DOI: https://doi.org/10.1038/191591b0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.