Structure of AgSCN.P(n-C3H7)3

Article metrics

Abstract

COMPLEXES of silver iodide with n-alkyl trisubstituted phosphines are tetrahedrally co-ordinated1. Complexes with trico-ordinated silver can be prepared with substituted alkyl–aryl phosphines2. Electronic effects due to alkyl substitution cannot be neglected, as factors which could influence the change in co-ordination3; however, their importance must not be over-emphasized2. In fact, silver (I) very easily changes its co-ordination according to the nature of co-ordinating groups, and the factors which affect the changes of stereochemistry are not at all clear4.

Access options

Rent or Buy article

Get time limited or full article access on ReadCube.

from$8.99

All prices are NET prices.

References

  1. 1

    Mann, G. F., Wells, A. F., and Purdie, D., J. Chem. Soc., 1829 (1937).

  2. 2

    Cass, R. C., Coates, G. E., and Hayter, R. G., J. Chem. Soc., 4007 (1955).

  3. 3

    Ahrland, S., and Chatt, J., Chem. and Indust., 96 (1955).

  4. 4

    Ahrland, S., Chatt, J., Davies, N. R., and Williams, A. A., J. Chem. Soc., 276 (1958).

  5. 5

    Turco, A., Panattoni, C., and Frasson, E., Ricerca Sci., 29, 545 (1959).

  6. 6

    Lindqvist, I., Acta Cryst., 10, 29 (1957).

  7. 7

    Lindqvist, I., and Strandberg, B., Acta Cryst., 10, 173 (1957).

  8. 8

    Luzzati, V., Acta Cryst., 5, 802 (1952).

  9. 9

    Zhdanov, G. S., and Zvonkova, Z. V., Usepkhi Khimi, 22 (1), 3 (1953).

  10. 10

    Cavalca, L., Nardelli, M., and Fava, G., Proc. Chem. Soc., 159 (1959).

  11. 11

    Owston, P. G., and Rowe, J. M., Acta Cryst., 13, 253 (1960).

  12. 12

    Chatt, J., Duncanson, L. A., Hart, L. A., and Owston, F. A., Nature, 181, 43 (1958).

  13. 13

    Pecile, C., Giacometti, G., and Tureo, A., Atti Accad. Lincei, 28, 189 (1960).

Download references

Author information

Rights and permissions

Reprints and Permissions

About this article

Cite this article

TURCO, A., PANATTONI, C. & FRASSON, E. Structure of AgSCN.P(n-C3H7)3 . Nature 187, 772–773 (1960) doi:10.1038/187772a0

Download citation

Further reading

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.