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Ionic-Covalent Bonding in Crystals

Nature volume 187, pages 590–591 (1960)Cite this article

Abstract

IN discussions in the literature regarding bonding in inorganic semiconducting (or insulating) crystals there seems to be some confusion between bond ionicity on one hand and charge separation effects due to electronegativity differences on the other. This appears to have arisen from the common assumption that the ionic component of bonding in solids is determined solely by the electronegativity difference (δx) between the constituent atoms (that is, that a compound with, say, δx = 1.0 must be more ionic than one with δx = 0.5). Without some qualification, this assumption can be very misleading.

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References

  1. Coulson, C. A., “Valence” (Oxford University Press, 1952).

    Google Scholar 

  2. Daudel, P., and Daudel, R., J. Phys. Radium, 7, 12 (1946).

    Article  CAS  Google Scholar 

  3. Sanderson, R. T., J. Amer. Chem. Soc., 74, 272 (1952).

    Article  CAS  Google Scholar 

  4. Pauling, L., “The Nature of the Chemical Bond” (Cornell University Press, New York, 1945).

    MATH  Google Scholar 

  5. Goodman, C. H. L., J. Electronics, 1, 115 (1955).

    CAS  Google Scholar 

  6. Sanderson, R. T., J. Chem. Educ., 29, 539 (1952).

    Article  CAS  Google Scholar 

  7. Sanderson, R. T., J. Inorg. Nucl. Chem., 7, 288 (1958).

    Article  CAS  Google Scholar 

  8. Matossi, F., Z. Naturforsch., 14 a, 791 (1959).

    ADS  Google Scholar 

  9. Wolff, G. A., and Broder, J. D., Acta Cryst., 12, 313 (1959).

    Article  CAS  Google Scholar 

  10. Braunstein, R., J. Phys. Chem. Solids, 8, 280 (1959).

    Article  ADS  CAS  Google Scholar 

  11. Goodman, C. M. L., J. Phys. Chem. Solids, 6, 305 (1958).

    Article  ADS  CAS  Google Scholar 

  12. Haïssinsky, M., J. Phys. Radium, 7, 7 (1946).

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Research Laboratories, The General Electric Co., Ltd., Wembley, England

    C. H. L. GOODMAN

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  1. C. H. L. GOODMAN
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GOODMAN, C. Ionic-Covalent Bonding in Crystals. Nature 187, 590–591 (1960). https://doi.org/10.1038/187590a0

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