Abstract
THE formation of a hexagonal modification of an electro-deposited chromium has been discussed since the first announcement was made. In 1935, L. Wright et al. 1 determined the conditions for the production of the hexagonal form from chromic acid baths, and recently C. A. Snavely2 fully examined the structural characteristics of the electro-deposited chromium from chromic acid baths containing sulphate ion.
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References
- 1
Wright, L., Hirst, H., and Riley, J., Discuss. Farad. Soc., 1253 (1935).
- 2
Snavely, C. A., Trans. Electrochem. Soc., 92, 537 (1947).
- 3
Siemense and Halske, Ger. Pat. 754,360, Nov. 6, 1933.
- 4
Ishida, T., Noda, Y., and Okada, H., J. Metal Finishing Soc. Japan, 10, 381 (1959).
- 5
Quaely, M. F., Proc. Fourteenth Ann. Conv. Amer. Electroplaters' Soc., 48 (1953).
- 6
Sasaki, K., and Sekito, S., J. Soc. Chem. Indust. Japan, 33, B, 482 (1930).
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OKADA, H., ISHIDA, T. Hexagonal Modification of Black Chromium Electro-deposit. Nature 187, 496–497 (1960) doi:10.1038/187496a0
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Further reading
-
Corrosion behavior of Cr electrodeposited from Cr(VI) and Cr(III)-baths using direct (DCD) and pulse electrodeposition (PED) techniques
Corrosion Science (2009)
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The present status of black chromium plating
Surface Technology (1981)
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