Letter | Published:

Microwave Spectra of Diazomethane and its Deutero Derivatives

Abstract

WE have measured rotation spectra, in the frequency-range 19,000–90,000 Mc./s., for three isotopic forms of diazomethane, and obtained the constants shown in Table 1, in Mc./s. A preliminary value of 1.45 D is obtained for the dipole moment of diazomethane from Stark effect measurements on the 000 → l01 transition. Nuclear quadrupole hyperfine structure is resolvable; its analysis is at present incomplete.

Access optionsAccess options

Rent or Buy article

Get time limited or full article access on ReadCube.

from$8.99

All prices are NET prices.

References

  1. 1

    Mills, I. M., and Thompson, H. W., Trans. Farad. Soc., 50, 1270 (1954).

  2. 2

    Fletcher, W. H., and Garrett, T. P., J. Chem. Phys., 25, 50 (1956).

  3. 3

    Johnson, H. R., and Strandberg, M. W. P., J. Chem. Phys., 20, 687 (1952).

  4. 4

    Boersch, H., Monatsh., 65, 331 (1935).

  5. 5

    Müller, E., and Kreutzmann, W., Ann., 512, 264 (1934).

Download references

Author information

Rights and permissions

Reprints and Permissions

About this article

Further reading

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.