Letter | Published:

Production of Vibrationally Excited Oxygen Molecules in the Flash Photolysis of Ozone

Nature volume 180, pages 12721273 (07 December 1957) | Download Citation



PREVIOUS work on the photolysis of ozone has led to the conclusion that a simple atom-chain mechanism is incapable of explaining the experimental facts. The existence of an energy chain involving excited oxygen molecules has gained wide acceptance due to the work of Schumacher1, Heidt and Forbes2, and Ritchie3. The nature of the excitation involved in the energy chain was not known, however, most workers assuming it to be the 1σ+g state of the oxygen4. Experiments on the flash photolysis of ozone5 have enabled us to show that the excitation is purely vibrational, the oxygen being formed in the ground electronic state with up to 16 quanta of vibrational energy, by reaction (1) which is exothermic to the extent of 93 kcal./mole for O(3P) and 138 kcal./mole for O(1D).

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  1. Department of Physical Chemistry, University of Cambridge. Aug. 22.

    • W. D. McGRATH
    •  & R. G. W. NORRISH


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