Abstract
THE flash photolysis technique1 has been used to examine the photochemical decomposition of lead tetramethyl. At an energy of 2,500 joules (50 µF.; 10 kV.) the decomposition of lead tetramethyl at pressures up to 12 mm. mercury was shown to be largely complete in 1.2 m.sec. after the initial light flash; this was the time for the reaction vessel to become opaque to light due to the deposition of a lead film. The contents of the quartz reaction vessel (volume 500 cm.3, surface/volume = 1.6) were examined in this interval by passing a second light flash through the length (1 metre) of the vessel into a large Littrow (Hilger E1) spectrograph using a slit width of 0.02 mm.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Rent or buy this article
Get just this article for as long as you need it
$39.95
Prices may be subject to local taxes which are calculated during checkout
References
Porter, G., Proc. Roy. Soc., A, 200, 284 (1949); Discuss. Farad. Soc., 9, 60 (1950).
Christie, M. I., and Porter, G., Proc. Roy. Soc., A, 212, 396 (1952).
Shull, E. R., Oakwood, T. S., and Rank, D. H., J. Chem. Phys., 21, 2024 (1953).
Lewis, G. N., Magel, T. T., and Lipkin, D., J. Amer. Chem. Soc., 62, 2975 (1940). Linschitz, H., Berry, M. G., and Schweitzer, D., J. Amer. Chem. Soc., 76, 5833 (1954).
Norman, I., and Porter, G., Proc. Roy. Soc., A, 230, 399 (1955).
Porter, G., and Windsor, M. W., Discuss. Farad. Soc., 17, 178 (1954). Porter, G., and Wright, F. J., Trans. Farad. Soc., 51, 1205 (1955).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
COOK, C., CLOUSTON, J. Absorption Spectra arising from the Photolysis of Lead Tetramethyl. Nature 177, 1178–1179 (1956). https://doi.org/10.1038/1771178a0
Issue Date:
DOI: https://doi.org/10.1038/1771178a0
This article is cited by
-
�ber eine unsymmetrische Vebreiterung der Bleiresonanzlinie
Die Naturwissenschaften (1962)
-
Absorption Spectra arising from the Photolysis of Lead Tetramethyl
Nature (1957)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.
