Abstract
IT has long been realized that the canonical form (Ia) may contribute significantly to the structure of the dithiocarbamate residue in its complex compounds, M(S2CNR 2)n, where M is a metal atom and n its valency, but no physical or chemical evidence for this has yet been advanced.
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References
Van der Kerk, G. J. M., and Klöpping, H. L., Rec. Trav. Chim., 71, 1179 (1952).
Van der Kerk, G. J. M., van Raalte, M. H., Sijpesteijn, A. K., and van der Veen, R., Nature, 176, 308 (1955).
Randall, H. M., Fowler, R. G., Fuson, N., and Dangl, J. R., “Infrared Determination of Organic Structures”, 5 (Van Nostrand, New York, 1949).
Mann, J., Trans. Inst. Rubber Indust., 27, 232 (1951).
Malatesta, L., Gazz. Chim. Ital., 69, 629 (1939); 70, 541 (1940).
Finn, A. E., Hampson, G. C., and Sutton, L. E., J. Chem. Soc., 1254 (1938).
cf. Zinc O-isopropylxanthate, Bellamy, L. J., “The Infra-red Spectra of Complex Molecules”, 294 (Methuen, London, 1954).
Tschamler, H., and Leutner, R., Monatsh., 83, 1502 (1952).
Krebs, H., Weber, E. F., and Fassbender, H., Z. anorg. Chem., 276, 128 (1954).
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CHATT, J., DUNCANSON, L. & VENANZI, L. Electronic Structures of Dithiocarbamates and Xanthates. Nature 177, 1042–1043 (1956). https://doi.org/10.1038/1771042b0
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DOI: https://doi.org/10.1038/1771042b0
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