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Structure of Sterculic Acid

Abstract

THE structure of sterculic acid, the major component of the kernel oil of Sterculia foetida, has attracted the attention of various workers. Hilditch et al. 1 failed to isolate the acid but concluded from the constants of the oil and the mixed methyl esters and some degradative experiments that it was 12-methyl octadeca-9: 11-dienoic acid. Steger and Van Loon2, working on the mixed fatty acids, deduced that it was probably a hydroxy acid, C18H34O3. However, recently Nunn3 has isolated this acid, C19H34O2, by the method of urea complexes and suggested its structure as ω -(2n-octylcycloprop-1-enyl)-octanoic acid (I).

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References

  1. Hilditch, Meara and Zaky, J. Soc. Chem. Indust., 60, 198T (1941).

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  2. Steger and Van Loon, Fette u. Seifen., 50, 305 (1943).

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  3. Nunn, J. Chem. Soc., 313 (1952).

  4. Kohler and Conant, J. Amer. Chem. Soc., 39, 1404 (1917).

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VERMA, J., NATH, B. & AGGARWAL, J. Structure of Sterculic Acid. Nature 175, 84–85 (1955). https://doi.org/10.1038/175084a0

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