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Physical chemistry

The protean proton in water

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  1. Agmon, N. Chem. Phys. Lett. 244, 456–462 (1995).

    Google Scholar 

  2. Marx, D., Tuckerman, M. E., Hutter, J. & Parrinello, M. Nature 397, 601–604 (1999).

    Article  ADS  CAS  Google Scholar 

  3. Ando, J. & Hynes, J. T. J. Mol. Liq. 64, 25–37 (1995).

    Google Scholar 

  4. Kohen, A. & Klinman, J. P. Acc. Chem. Res. 31, 397–404 (1998).

    Google Scholar 

  5. Cleland, W. W. & Kreevoy, M. M. Science 264, 1887–1890 (1994).

    Google Scholar 

  6. Pomes, R. & Roux, B. Chem. Phys. Lett. 234, 416–424 (1995).

    Google Scholar 

  7. Bianco, R. & Hynes, J. J. Phys. Chem. A 102, 309–314 (1998).

    Google Scholar 

  8. Eigen, M., Kruse, W. & De Maeyer, L. Prog. React. Kin. 2, 285–318 (1964).

    Google Scholar 

  9. Kochanksi, E., Kelterbaum, R., Klein, S., Rohmer, M. M. & Rahmouni, A. Adv. Quantum Chem. 28, 273–291 (1997).

    Google Scholar 

  10. Zundel, G. in The Hydrogen Bond - Recent Developments in Theory and Experiments II(eds Schuster, P., Zundel, G. & Sandorfy, C.) 683-766 (North Holland, Amsterdam, 1976).

  11. Luz, Z. & Meiboom, S. J. Am. Chem. Soc. 86, 4768–4769 (1964).

    Google Scholar 

  12. Newton, M. J. Chem. Phys. 67, 5535–5546 (1977).

    Google Scholar 

  13. Vuilleumier, R. & Borgis, D. J. Phys. Chem. B 102, 4261–4264 (1998).

    Google Scholar 

  14. Schmitt, U. W. & Voth, G. A. J. Phys. Chem. B 102, 5547–5551 (1998).

    Google Scholar 

  15. Limbach, H. -H. & Manz, J. (eds Ber. Bunsenges. Phys. Chem. 102, 289–586 (1998).

    Google Scholar 

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Hynes, J. The protean proton in water. Nature 397, 565–567 (1999).

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