Abstract
NUMEROUS investigators have studied the reaction of Grignard reagents with anhydrous ferric chloride, but have failed to isolate any organo-iron compounds or to produce any definite evidence for their formation in such reactions.
This is a preview of subscription content
Access options
Subscribe to Journal
Get full journal access for 1 year
$199.00
only $3.90 per issue
All prices are NET prices.
VAT will be added later in the checkout.
Tax calculation will be finalised during checkout.
Buy article
Get time limited or full article access on ReadCube.
$32.00
All prices are NET prices.
References
Job and Reich, C.R. Acad. Sci., Paris, 174, 1358 (1922).
Champetier, Bull. Soc. chim. France, [4], 47, 1131 (1930).
Gilman and Lichtenwalter, J. Amer. Chem. Soc., 61, 957 (1939).
Brown, Nature, 165, 566 (1950).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
KEALY, T., PAUSON, P. A New Type of Organo-Iron Compound. Nature 168, 1039–1040 (1951). https://doi.org/10.1038/1681039b0
Issue Date:
DOI: https://doi.org/10.1038/1681039b0
Further reading
-
Electrochemically driven regioselective C−H phosphorylation of group 8 metallocenes
Nature Communications (2022)
-
Synthesis and characterization of ferrocene-based thiosemicarbazones along with their computational studies for potential as inhibitors for SARS-CoV-2
Journal of the Iranian Chemical Society (2022)
-
Jack D. Dunitz (1923–2021): a chemists’ crystallographer
Structural Chemistry (2022)
-
Isolation and electronic structures of derivatized manganocene, ferrocene and cobaltocene anions
Nature Chemistry (2021)
-
Neutral all metal aromatic half-sandwich complexes between alkaline earth and transition metals: an ab initio exploration
Structural Chemistry (2021)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.
