Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Degradation of a Vinylidene Chloride Copolymer in Solution

Abstract

SOME observations have recently been made on the changes in viscosity of solutions of a copolymer containing approximately 85 per cent vinylidene chloride, 13 per cent vinyl chloride and 2 per cent acrylonitrile (by weight). The polymer was soluble in hot, but not in cold, tetrahydrofuran : once it had been dissolved by heating in the solvent at 60–65° C. for 2–3 min., the solution could be cooled to room temperature without gelling or precipitation.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Morrison, Holmes and McIntosh, Can. J. Res., 24 B, 5, 179 (1946).

    Google Scholar 

  2. Sirianni, Wise and McIntosh, Can. J. Res., 25 B, 3, 301 (1947).

    Google Scholar 

  3. Naunton, Trans. Farad. Soc., 38, 332 (1942).

    Article  Google Scholar 

  4. Lacau and Magat, Farad. Soc. Discussion, "The Labile Molecule" (Sept. 1947).

  5. Cf. Mesrobian and Tobolsky, J. Polymer Sci., 2, 463 (1947).

    Article  ADS  CAS  Google Scholar 

  6. Mead and Fuoss, J. Amer. Chem. Soc., 64, 277 (1942).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

JACKSON , D., REID , W. Degradation of a Vinylidene Chloride Copolymer in Solution. Nature 162, 29–30 (1948). https://doi.org/10.1038/162029b0

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/162029b0

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing