Degradation of a Vinylidene Chloride Copolymer in Solution

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Abstract

SOME observations have recently been made on the changes in viscosity of solutions of a copolymer containing approximately 85 per cent vinylidene chloride, 13 per cent vinyl chloride and 2 per cent acrylonitrile (by weight). The polymer was soluble in hot, but not in cold, tetrahydrofuran : once it had been dissolved by heating in the solvent at 60–65° C. for 2–3 min., the solution could be cooled to room temperature without gelling or precipitation.

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References

  1. 1

    Morrison, Holmes and McIntosh, Can. J. Res., 24 B, 5, 179 (1946).

  2. 2

    Sirianni, Wise and McIntosh, Can. J. Res., 25 B, 3, 301 (1947).

  3. 3

    Naunton, Trans. Farad. Soc., 38, 332 (1942).

  4. 4

    Lacau and Magat, Farad. Soc. Discussion, "The Labile Molecule" (Sept. 1947).

  5. 5

    Cf. Mesrobian and Tobolsky, J. Polymer Sci., 2, 463 (1947).

  6. 6

    Mead and Fuoss, J. Amer. Chem. Soc., 64, 277 (1942).

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JACKSON , D., REID , W. Degradation of a Vinylidene Chloride Copolymer in Solution. Nature 162, 29–30 (1948) doi:10.1038/162029b0

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