Abstract
IN a previous letter1 it was reported that the structure of Br III was detected, the intervals of the fundamental term 5s 4P being 2589 cm.1 and 2253 cm.1. A further comprehensive investigation, carried out particularly to distinguish between the lines of Br II and Br III, has led to a considerable extension of the scheme, which consists of doublets and quartets of the 4p, 5p, 5s, 4d and 5d configurations. On account of the large intervals of the 4d and 5d configurations, it is difficult to assign the L-values to these terms. Assuming an arbitrary value of 300,000 cm.1 for 4p 4S1½, some of the chief term values are:
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NATURE, 135, 309 (1935).
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RAO, K. Structure of Bromine III. Nature 138, 168 (1936). https://doi.org/10.1038/138168c0
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DOI: https://doi.org/10.1038/138168c0
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