Abstract
X-RAY studies, carried out in this Institute, have shown that when the spinel, MgO.Al2O3, dissolves Al2O3, the oxygen excess is caused by the occurrence of vacant points in the metal lattices. In accordance with this, -Al2O3, the unstable limit of these solid solutions, represents a spinel lattice where 1/9 of the metal positions are vacant.
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HÄGG, G. The Spinels and the Cubic Sodium-Tungsten Bronzes as New Examples of Structures with Vacant Lattice Points. Nature 135, 874 (1935). https://doi.org/10.1038/135874b0
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DOI: https://doi.org/10.1038/135874b0
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