Abstract
ABOUT twenty years ago, O. Olsson-Collenberg1 synthesised a series of alkali tungsten chlorides with trivalent tungsten of the general formula M3W2Cl9. Later, Collenberg and Sandved2 found that water solutions of these compounds contain the complex ion W2Cl9. An X-ray analysis of these chlorides has now shown that this ion is present also in their crystals.
Similar content being viewed by others
Article PDF
References
Thesis, Uppsala, 1914.
Z. anorg. allg. Chemie, 130, 1; 1923.
J. Chem. Phys., 3, 117; 1935.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
BROSSET, C. Crystal Structure of some Alkali Tungsten Chlorides. Nature 135, 874 (1935). https://doi.org/10.1038/135874a0
Issue Date:
DOI: https://doi.org/10.1038/135874a0
This article is cited by
-
F. Albert Cotton (1930–2007)
Structural Chemistry (2007)
-
Delta bonds and rotational barriers in 4d and 5d metal-porphyrin dimers
Journal of Cluster Science (1994)
-
Metal Clusters in a New Mixed Halide of Molybdenum (IV) and (V)
Nature (1966)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.