Letter | Published:

The Limiting Mobilities of some Monovalent Ions and the Dissociation Constant of Acetic Acid at 25°

Naturevolume 130page435 (1932) | Download Citation



MACINNES, Shedlovsky, and Longsworth 1 claim to have obtained accurate figures for the limiting mobilities of certain monovalent ions, inter alia, K+, 73.50; Na+, 50.10; H+, 349.72; Cl-, 76.32; CH3COO-, 40.87 ; and they refer to the discrepancies between these and the older figures compiled by Noyes and Falk.2 We would point out that all these constants, except that for the acetate, were determined by us some time ago,3 and were based on the use of the Ferguson and Vogel method4 for extrapolation to infinite dilution and a value of 0.490 for the cation transport number for potassium chloride ; our figures are K+, 73.4 ; Na+, 49.8 ; H+, 348.0 ; Cl-, 76.4, that for the hydrogen ion being based on conductivity measurements of iodic, hydrochloric, and benzenesulphonic acids in dilute solution in silica cells.

Access optionsAccess options

Rent or Buy article

Get time limited or full article access on ReadCube.


All prices are NET prices.


  1. 1

    J. Amer. Chem. Soc., 54, 2761; 1932.

  2. 2

    J. Amer. Chem. Soc., 34, 454; 1912.

  3. 3

    J. Chem. Soc., 1751; 1931: 400; 1932

  4. 4

    Phil. Mag., 50, 971; 1925.

  5. 5

    J. Amer. Chem. Soc., 54, 1429; 1932.

Download references

Author information


  1. Woolwich Polytechnic, London, S.E.18.

    • A. I. VOGEL
  2. University College, Southampton

    • G. H. JEFFERY


  1. Search for A. I. VOGEL in:

  2. Search for G. H. JEFFERY in:

About this article

Publication history

Issue Date




By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.