Temporal control over self-assembly processes is a desirable trait for discovering adaptable and controllable materials. Here the authors show that a chemical fuel driven system can not only self-assemble in a controlled manner, but can also result in precise control over the assembly and disassembly kinetics.

Cubic crystalline single networks of large open-space lattices are ubiquitous in nature. Here the authors show that the topology of the circumferential bilayer of polymer cubosomes differentiates between two non-intersecting pore networks embedded in the cubic mesophase by sealing one channel network at the interface.

A perylene diimide derivative shows nonlinear chemical dynamics when chemically fuelled in a semi-batch reactor.

There is a continual pursuit for different ways to detect counterfeiting in today’s society. Here the authors show photo-responsive supramolecular polymers can be used in fluorescent anti-counterfeit applications, by taking advantage of multicycle anthracene‒endoperoxide switching properties.

Chiral supramolecules may be used in chiral recognition, sensing and catalysis. Here the authors selectively synthesized homochiral and heterochiral supramolecular biocoordination polymers of naphthalene diimide ligands with alanine termini and Zn ions.