Chemical physics articles from across Nature Portfolio

Surface heterogeneities lead to friction between droplets and solid surfaces, limiting the performance of the latter in a number of applications. A combination of friction force measurements and atomistic molecular dynamics simulations now sheds light on the influence of molecular scale heterogeneities on droplet friction.

Electric fields offer an easy means to manipulate liquid metal droplets. Now, directed droplet transfer between immersed electrodes is achieved in an alkaline electrolyte without electrical short circuit.

The correlation between asymmetric molecular geometry of non-fullerene acceptors and their optoelectronic properties was unclear. Here, the authors found asymmetric ones exhibit increased open-circuit voltage compared to their symmetric counterparts due to reduced non-radiative charge recombination.

Photosynthesis in biological systems occurs in a noisy environment that reduces the lifetime of coherences in the excitation energy transfer. Here the author demonstrate that long-lasting coherences are protected by quantum phase synchronization, realized in dimers by exciton-vibrational coupling where energy dissipation occurs predominantly in resonant anti-symmetric collective modes.

As amorphous solids, glasses and gels are similar, but the origins of their different elastic properties are unclear. Simulations now suggest differing free-energy-minimizing pathways: structural ordering for glasses and interface reduction for gels.

Surface heterogeneities lead to friction between droplets and solid surfaces, limiting the performance of the latter in a number of applications. A combination of friction force measurements and atomistic molecular dynamics simulations now sheds light on the influence of molecular scale heterogeneities on droplet friction.

Electric fields offer an easy means to manipulate liquid metal droplets. Now, directed droplet transfer between immersed electrodes is achieved in an alkaline electrolyte without electrical short circuit.

A promising pathway towards the laser cooling of a molecule containing a radioactive atom has been identified. The unique structure of such a molecule means that it can act as a magnifying lens to probe fundamental physics.

An article in Nature Chemistry discovers that the two light-controlled isomers of azobenzene also have very different rupture forces.

Despite advances, understanding of the quantum state-to-state scattering dynamics between charged ions and neutral molecules at low collision energies remains limited. A high-resolution crossed-beam experiment with quantum state-selected ions prepared by laser photoionization and supporting trajectory surface-hopping calculations now provides insight into the quantum state-to-state collisional dynamics of a model charge-transfer reaction.