Letter


Nature Physics 1, 50 - 52 (2005)
doi:10.1038/nphys106

Subject Categories: Statistical physics, thermodynamics and nonlinear dynamics | Materials physics

Maximum angle of stability of a wet granular pile

Sarah Nowak1, Azadeh Samadani1,2 and Arshad Kudrolli2


Anyone who has built a sandcastle recognizes that adding liquid to the sand grains increases the overall stability. However, measurements of the stability in wet granular materials often conflict with theory and with each other1, 2, 3, 4, 5, 6, 7. The friction-based Mohr–Coulomb model3, 8 distinguishes between granular friction and interparticle friction, but uses the former without providing a physical mechanism. A frictionless model for the geometric stability of dry particles on the surface of a pile2 is in excellent agreement with experiment. However, the same model applied to wet grains overestimates the stability and predicts no dependence on system size. Here we take a frictionless liquid-bridge model and perform a stability analysis within the pile. We reproduce our experimentally observed dependence of the stability angle on system size, particle size and surface tension. Furthermore, we account for past discrepancies in experimental reports by showing that sidewalls can significantly increase the stability of granular material.


The experimental apparatus consisted of a clear plexiglass drum that was rotated about a horizontal axis. We primarily used a drum with a diameter D of 28.5 cm and a width W that could be varied from 0 to 14.5 cm. A drum with D=12.5 cm and W=11.5 cm was also used, to vary system size. The rotation rate omega was varied from 9.0times10-4 to 5.6times10-1 r.p.m. Soda-lime glass spheres with density rho of 2.4 g cm-3, radii r=0.25,0.3,0.5 and 1.5 mm and size dispersity within 0.1 mm were used. The drum was 40% filled with grains premixed with a small amount of liquid. We report the amount of liquid added in terms of the volume fraction, Vf, which is defined as the volume of the liquid divided by the volume occupied by the grains alone. The effect of surface tension of the liquid Gamma was tested by using silicone oil and water, which have Gamma=20plusminus1 and 70plusminus1 dyn cm-1, respectively. Silicone oil with viscosity nu ranging from 5 to 1,000 cS was used to study its impact on the measured inclination angles.

The drum was back lit so that light could pass through a thin layer of grains that tended to accumulate on the sides of the drum, but was unable to pass through the bulk of the pile. Images were acquired with a digital camera of mega-pixel resolution at a rate of three frames per second and these were used to determine the surface slope with automated code. At this rate, the slope of the pile changed by no more than 0.2° between frames. This error in measurement is not significant given that the slope of the pile at the moment of avalanche was distributed over about two degrees in a given run. At least 30 events were recorded to measure the mean values. The error bars in Figs 2 and 4 correspond to the r.m.s. of the mean angles measured over five experimental runs, each consisting of at least 30 avalanche events.

A stick–slip avalanche regime or a continuous avalanche regime is observed depending on the rotation rate of the drum and the liquid viscosity (see Fig. 1). In the stick–slip regime, the slope of the pile increases linearly with time until the heap reaches the maximum angle thetam. At this point, the grains are observed to avalanche and the pile's angle decreases to the angle of repose, thetar, when avalanching stops. In the continuous avalanche regime, the grains are observed to flow continuously and the slope of the pile is approximately constant over time. By changing omega and nu, one can change from the stick–slip to the continuous avalanche regime. thetam in the stick–slip regime is observed to be independent of omega and nu within the fluctuations in the data and thus is rate independent. On the other hand, thetar and the surface angle in the continuous avalanche depend on the viscosity, consistent with other observations6. The overall behaviour as a function of omega is similar to systematic investigations with a rotated drum7, but the magnitudes are significantly lower.

Figure 1: Avalanching regimes.

Figure 1 : Avalanching regimes.

Glass spheres (r=0.5 mm) mixed with silicone oil in a rotating drum (W=14.5 cm). a, Stick–slip flow is observed for omega=0.028 r.p.m. and viscosity nu=5 cS. b, Continuous flow is observed for omega=0.28 r.p.m. and nu=5 cS.

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We note that empirically, as a function of Vf, thetam increases sharply, and saturates when Vf is of the order of 1times103thetam (see Fig. 2a). The dependence of the angles on Vf is again qualitatively consistent with other studies6, 7, but the overall increase and saturation is significantly lower. At very small Vf, thetam can be sensitive to Vf because of the inherent roughness of the grains and its impact on the shape of the liquid bridge1. We performed our experiments in the saturation regime, so that such effects were eliminated, but we also chose a small enough Vf so that the liquid did not drain to the bottom because of gravity, which would cause spatial inhomogeneity.

Figure 2: Impact of liquid volume fraction and drum width on stability.

Figure 2 : Impact of liquid volume fraction and drum width on stability.

a, Measured surface angles as a function of Vf of silicone oil (nu=5 cS, r=0.5 mm, omega=0.028 r.p.m.). b, thetam is observed to decay exponentially as W is increased. An error bar is indicated on one of the points (Vf=8times10-3, fitting parameters a0=23.3°, b0=0.33 cm-1, c0=30°).

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We determined experimentally that higher angles can be attributed to significant wall effects when narrow widths are used, as in most other investigations. For example, the angles reported in ref. 10,11 are 15–20° higher than those we report for similar r and Gamma, but the apparatus was 3.2 cm wide. The observed dependence on W is plotted in Fig. 2b and is described by an exponential fit. The effect of side walls on grains that are fully immersed in a liquid has been reported in ref. 9. The data in that case reach the asymptotic value for a W of a few grain diameters because liquid bridges are absent. However, the side walls have an effect over many hundred times the diameter of the particle in the partially saturated case because of the added particle–particle correlations induced by the liquid bridges. In order to simplify the analysis, we examine the data only for W>11.5 cm where the side walls are unimportant.

A thetam of at least 90° is predicted in ref. 2 if the ratio of the capillary to gravitational force, which is also called the bond number (Bo; ref. 5), is of order one or greater. Now the capillary force caused by the liquid-bridge bond is given by

Unfortunately we are unable to provide accessible alternative text for this. If you require assistance to access this image, or to obtain a text description, please contact npg@nature.com

where alpha is a dimensionless constant that depends on the size and shape of the liquid bridge between the particles, and their separation10, 11. Although there is some ambiguity in the value of alpha, it is of order 1, and therefore Bo is approximately 5 for glass beads with r=0.5 mm mixed with silicone oil at Vf=0.008. We do not observe thetam to reach 90°; the piles typically avalanche when theta exceeds 30° as can be noted from Fig. 1. We believe that the discrepancy arises from the assumption that a wet granular pile fails at the surface, as was also noted in ref. 3.

Following ref. 2, let us consider the stability of a sphere placed on top of three base spheres that are all in contact with each other (see Fig. 3). In the absence of liquid bridges, the sphere becomes unstable when the gravitational force is outside the triangle formed by the base spheres. By averaging over all possible orientation angles phi of the base triangle between 0 and 60°, in ref. 2 it was shown that the average inclination thetad (the geometric or dry angle of stability) is 23.8°. At this angle, approximately half of the triangular bases at the surface can support a sphere and thus the pile will be stable. Measurements with dry glass, plastic or steel spheres in a rotated drum all show thetam that are within a few degrees of their prediction, and thus it seems that the complications associated with random packing and friction between particles need not be taken into account to obtain reasonable results.

Figure 3: The liquid-bridge model.

Figure 3 : The liquid-bridge model.

a, A schematic of the system. b, The geometrical arrangement of one sphere resting on top of three spheres in contact, as used in the stability analysis. Liquid bridges located at the points of contact introduce forces along the segments joining the vertices abcd of the tetrahedron at which the spheres are centred.

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Let us again consider a sphere resting on three base spheres (as in Fig. 3b) that is located at a distance x and angle theta from the bottom of the inclined surface. For theta>thetad, the sphere will be gravitationally unstable. Now we assume that, on average, it is the component of the liquid-bridge bond ab directed up the inclined plane tilted at theta that is responsible for offsetting the unbalanced gravitation component down the plane. (We neglect the contributions of the bonds ac and ad because they are mostly directed towards the axis around which the top sphere rotates when it becomes unstable.)

Because abcd forms a tetrahedron, the projection of the force Fc up the plane of the base triangle because of the liquid bridge between ab can be easily determined. The average component of the liquid bond force corresponding to the average orientation angle phi of the base triangle is given by Unfortunately we are unable to provide accessible alternative text for this. If you require assistance to access this image, or to obtain a text description, please contact npg@nature.com, which is approximately 0.46Fc. Therefore, the shear stress that can be supported by the liquid bridges along the theta plane is given by the calculated force per sphere multiplied by the average number of spheres per unit area. Now, the number of particles per unit volume is 3fp/4pir3, where fp is the packing fraction of the grains, which is approximately 0.64 for spherical grains. Therefore, the number of particles per unit area is equal to the number of particles per unit volume raised to the 2/3 power. We then have the shear stress

Unfortunately we are unable to provide accessible alternative text for this. If you require assistance to access this image, or to obtain a text description, please contact npg@nature.com

where Fc is given by equation (1).

Now let us calculate the shear stress owing to the unbalanced weight of a thin vertical volume element above a plane tilted at theta and located at a distance x from the bottom of the surface, as shown in Fig. 3a. We can write the unbalanced weight as

Unfortunately we are unable to provide accessible alternative text for this. If you require assistance to access this image, or to obtain a text description, please contact npg@nature.com

where M is the mass of the volume element that has a length dx, width W and a height xsin(thetam-theta)/costhetad, and g is the acceleration due to gravity. We take (theta-thetad) in equation (2) because the pile is geometrically stable up to thetad. Thus we find that the shear stress on the theta plane from the weight of the volume element is

Unfortunately we are unable to provide accessible alternative text for this. If you require assistance to access this image, or to obtain a text description, please contact npg@nature.com

To simplify further discussion, we take the small-angle approximation, and obtain the unbalanced stress to be

Unfortunately we are unable to provide accessible alternative text for this. If you require assistance to access this image, or to obtain a text description, please contact npg@nature.com

Now for each x it can be shown that this shear stress is maximum for theta=(thetam+thetad)/2. This is simply because, as one goes above thetad, on the one hand there is less material above, but on the other the volume element is tilted further from equilibrium.

It is not clear whether the pile will fail when the shear stress from the weight first exceeds the stress provided by the liquid bridges, or when the average shear stress owing to the weight of the pile exceeds the stress provided by the liquid bridges. In reality, the correct physical situation is most probably a combination of these two. Therefore, we set x=betaL in equation (4) when balancing the stresses, where beta is a dimensionless constant between 0.5 and 1, and L is the length of the pile's surface. If adjacent volume elements cannot offset any stress by a particular volume element then, beta=1, and if the stress is evenly distributed along the slip plane then beta=0.5. Given the variance seen in the stick–slip events (see Fig. 1a), and the heterogeneity of the pile at the granular level, beta may vary from event to event.

Combining these facts and balancing the two stress components, we obtain the condition for equilibrium,

Unfortunately we are unable to provide accessible alternative text for this. If you require assistance to access this image, or to obtain a text description, please contact npg@nature.com

and, setting alpha0=alpha/beta, we obtain

Unfortunately we are unable to provide accessible alternative text for this. If you require assistance to access this image, or to obtain a text description, please contact npg@nature.com

Figure 4a shows a comparison of the measured thetam as a function of particle size r and the fit to equation (5) after conversion of the units to degrees. The data are well described by using alpha0=1.2plusminus0.05. To further test the model, we measured thetam in two different-sized systems (L=27 and 12.5 cm) with various combinations of Gamma and r. Figure 4b shows a plot of the experimentally measured thetam above thetad compared with equation (5), with alpha0=1.2. Excellent overall agreement is observed.

Figure 4: Comparison of the measured data with the liquid-bridge model.

Figure 4 : Comparison of the measured data with the liquid-bridge model.

a, The maximum angle of stability for glass spheres mixed with water (L=27 cm). The solid line shows a fit to equation (5) with alpha0=1.2. b, The experimentally measured theta-thetad are plotted against the theoretical values calculated from equation (5). Key: silicone oil in the large drum (circle), water in the large drum (square), silicone oil in the small drum (triangle up), water in the small drum (triangle down). Filled shapes, open shapes and shapes with a times sign correspond to radii r=1.5,0.5 and 0.3 mm, respectively.

Full size image (8 KB)

We note that the small-angle approximation used to simplify equation (3) is reasonable over the angles tested. The analysis can be extended to higher angles without using this approximation, but thetam has to be obtained by a numerical solution of the corresponding equation. In developing our analysis, we have ignored the contribution of friction that will also help stabilize the wet pile. However, just as in the dry case, we may expect the friction contribution to be small as a grain rolls after being dislodged from the triangular base. A more detailed knowledge of how the failure develops may clarify this issue.

Our analysis captures the observed stability dependence on grain size, system size and surface tension. It would be of great interest to consider how well this analysis extends to piles composed of non-spherical and multisized grains as in natural sand.

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Acknowledgements

We thank J. Norton and N. Israeloff for their help with the apparatus, and J. Bico for feedback on the manuscript. The work was supported by the National Science Foundation Grant No. DMR-9983659, and the GLUE program of the Department of Energy.

Competing interests statement:

The authors declare that they have no competing financial interests.

Received 14 April 2005; Accepted 2 August 2005; Published online 29 September 2005.

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References

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  1. Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA
  2. Department of Physics, Clark University, Worcester, Massachusetts 01610, USA

Correspondence to: Arshad Kudrolli2 e-mail: akudrolli@clarku.edu

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