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Volume 9 Issue 3, March 2014

Silicon anodes have been actively researched for applications in lithium batteries because they have ten times the theoretical capacity of their carbon-based counterpart. Unfortunately nanostructured silicon anodes have challenging drawbacks, such as a large volume change during cycling, side reactions with the electrolyte and low volumetric capacity. Yi Cui and colleagues now show that these problems can be alleviated by using a hierarchically structured silicon anode whose design was inspired by a pomegranate. Silicon nanoparticles are first enclosed within a carbon shell, which allows them to freely expand and contract during cycling. These silicon-containing shells are then grouped together and surrounded by a thicker outer carbon layer that protects them from the electrolyte, yet lithium exchange with the solution phase still occurs. The cover is an artist's impression of these hierarchical structures.

Letter p187

IMAGE: NIAN LIU

COVER DESIGN: ALEX WING

Editorial

  • A series of national initiatives over the past 10 years has created a thriving nanoscience research environment in Australia.

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Thesis

  • Ten years after the publication of an influential report on the uncertainties in nanoscale science and engineering, Andrew D. Maynard asks, are we in danger of creating a new metaphorical grey goo?

    • Andrew D. Maynard
    Thesis
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Research Highlights

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News & Views

  • A commercially viable method for synthesizing magnetic nanoparticles could be developed by transferring clusters of genes from magnetic bacteria to foreign, more stable bacteria.

    • Sarah Staniland
    News & Views
  • Individual molecules change their conformation on application of an anisotropic compressive stress from the tip of an atomic force microscope.

    • Claus A. M. Seidel
    • Ralf Kühnemuth
    News & Views
  • Nanomechanical cantilevers can determine the concentration of active drugs in human serum.

    • F. Huber
    • H. P. Lang
    • Ch. Gerber
    News & Views
  • Quantum computers require error correction protocols to repair the state of the quantum bits. This has now been demonstrated using a 'majority voting' protocol among a cluster of three defect spins in diamond.

    • John J. L. Morton
    • Jeroen Elzerman
    News & Views
  • A design that allows electrical contacts to be created on semiconductor microphotonic structures brings quantum networks based on semiconductor single photon sources one step closer.

    • Ruth Oulton
    News & Views
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