Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • News & Views
  • Published:

Thermodynamics

Highs and lows in the density of water

Water contracts when it is cooled but, unlike other liquids, it then starts to expand at temperatures a few degrees above the melting point of ice. However, a new experimental study suggests that normal behaviour returns if the water is supercooled to low enough temperatures.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Comparison of the thermodynamic properties of supercooled liquid water and supercooled tellurium.

References

  1. Stanley, H. E. & Debenedetti, P. G. Phys. Today 56, 40–46 (June 2003).

    Google Scholar 

  2. Mishima, O. & Stanley, H. E. Nature 396, 329–335 (1998).

    Article  CAS  Google Scholar 

  3. Faraone, A., Liu, L., Mou, C.-Y., Yen C.-W. & Chen, S.-H. J. Chem. Phys. 121, 10843 (2004).

    Article  CAS  Google Scholar 

  4. Liu, D. et al. Proc. Natl Acad. Sci. USA 104, 9570–9574 (2007).

    Article  CAS  Google Scholar 

  5. Paschek, D. Phys. Rev. Lett. 94, 217802 (2005).

    Article  Google Scholar 

  6. Poole, P. H, Saika-Voivod, I. & Sciortino, F. J. Phys. Condens. Mat. 17, L431–L437 (2005).

    Article  CAS  Google Scholar 

  7. Fuentevilla, D. A. & Anisimov, M. A. Phys. Rev. Lett. 97, 195702 (2006).

    Article  CAS  Google Scholar 

  8. Speedy, R. J. J. Phys. Chem. 86, 982 (1982).

    Article  CAS  Google Scholar 

  9. Rault, J., Neflati, R. & Judenstein, P. Eur. Phys. J. B 36, 627–637 (2003).

    Article  CAS  Google Scholar 

  10. Hemmati, M., Moynihan, C. T. & Angell, C. A. J. Phys. Chem. B 115, 6663–6671 (2001).

    Article  CAS  Google Scholar 

  11. Kanno, H. Yokoyama, H. & Yoshimura, Y. J. Phys. Chem. B 105, 2019 (2001).

    Article  CAS  Google Scholar 

  12. Xu, L., Ehrenberg, I., Buldyrev, S. V. & Stanley, H. E. J. Phys. Condens. Mat. 18, S2239–S2246 (2006).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Angell, A. Highs and lows in the density of water. Nature Nanotech 2, 396–398 (2007). https://doi.org/10.1038/nnano.2007.201

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/nnano.2007.201

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing