Article abstract
Nature Materials 7, 158 - 164 (2008)
Published online: 20 January 2008 | doi:10.1038/nmat2102
Subject Categories: Polymers | Optical, photonic and optoelectronic materials | Materials for energy | Nanoscale materials
Morphology evolution via self-organization and lateral and vertical diffusion in polymer:fullerene solar cell blends
Mariano Campoy-Quiles1, Toby Ferenczi1, Tiziano Agostinelli2, Pablo G. Etchegoin3, Youngkyoo Kim1,4, Thomas D. Anthopoulos1, Paul N. Stavrinou1, Donal D. C. Bradley1 & Jenny Nelson1
Abstract
Control of blend morphology at the microscopic scale is critical for optimizing the power conversion efficiency of plastic solar cells based on blends of conjugated polymer with fullerene derivatives. In the case of bulk heterojunctions of regioregular poly(3-hexylthiophene) (P3HT) and a soluble fullerene derivative ([6,6]-phenyl C61-butyric acid methyl ester, PCBM), both blend morphology and photovoltaic device performance are influenced by various treatments, including choice of solvent, rate of drying, thermal annealing and vapour annealing. Although the protocols differ significantly, the maximum power conversion efficiency values reported for the various techniques are comparable (4–5%). In this paper, we demonstrate that these techniques all lead to a common arrangement of the components, which consists of a vertically and laterally phase-separated blend of crystalline P3HT and PCBM. We propose a morphology evolution that consists of an initial crystallization of P3HT chains, followed by diffusion of PCBM molecules to nucleation sites, at which aggregates of PCBM then grow.
- Department of Physics, Blackett Laboratory, Imperial College London, Prince Consort Road, London SW7 2BW, UK
- Dipartimento di Elettronica e Informazione, Politecnico di Milano, Pza L. Da Vinci 32, 20133, Milano, Italy
- The MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington, New Zealand
- Organic Nanoelectronics Laboratory, Department of Chemical Engineering, Kyungpook National University, Daegu 702-701, South Korea
Correspondence to: Mariano Campoy-Quiles1 e-mail: M.Campoy@imperial.ac.uk
Correspondence to: Donal D. C. Bradley1 e-mail: D.Bradley@imperial.ac.uk
Correspondence to: Jenny Nelson1 e-mail: Jenny.Nelson@imperial.ac.uk
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