Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Towards woven logic from organic electronic fibres

Abstract

The use of organic polymers for electronic functions is mainly motivated by the low-end applications, where low cost rather than advanced performance is a driving force. Materials and processing methods must allow for cheap production. Printing of electronics using inkjets1 or classical printing methods has considerable potential to deliver this. Another technology that has been around for millennia is weaving using fibres. Integration of electronic functions within fabrics, with production methods fully compatible with textiles, is therefore of current interest, to enhance performance and extend functions of textiles2. Standard polymer field-effect transistors require well defined insulator thickness and high voltage3, so they have limited suitability for electronic textiles. Here we report a novel approach through the construction of wire electrochemical transistor (WECT) devices, and show that textile monofilaments with 10–100 μm diameters can be coated with continuous thin films of the conducting polythiophene poly(3,4-ethylenedioxythiophene), and used to create micro-scale WECTs on single fibres. We also demonstrate inverters and multiplexers for digital logic. This opens an avenue for three-dimensional polymer micro-electronics, where large-scale circuits can be designed and integrated directly into the three-dimensional structure of woven fibres.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Pictures of planar and cylindrical electrochemical transistors (ECTs).
Figure 2: Electrical characteristics of electrochemical transistors.
Figure 3: Design and construction of logic circuits.
Figure 4: Design and electrical characterization of logic circuits on fibres.

Similar content being viewed by others

References

  1. Sirringhaus, H. et al. High-resolution inkjet printing of all-polymer transistor circuits. Science 290, 2123–2126 (2000).

    Article  CAS  Google Scholar 

  2. Service, R. F. Technology—electronic textiles charge ahead. Science 301, 909–911 (2003).

    Article  CAS  Google Scholar 

  3. Lee, J. B. & Subramanian, V. Weave patterned organic transistors on fiber for e-textiles. IEEE Trans. Electron Dev. 52, 269–275 (2005).

    Article  CAS  Google Scholar 

  4. Brian Farrell, P. W. N., Teverovsky, J., Slade, J. & Powell, M. Method of manufacturing a fabric article to include electronic circuitry and an electrically active textile article. US patent 6,729,025 (Foster-Miller, USA, 2001).

  5. E. Rehmi Post, N. G. Method of making flexible electronic circuitry. US patent 6,493,933 (Massachusetts Institute of Technology, USA, 2000).

  6. Kuhn, H. H., Child, A. D. & Kimbrell, W. C. Toward real applications of conductive polymers. Synth. Met. 71, 2139–2142 (1995).

    Article  CAS  Google Scholar 

  7. Hong, K. H., Oh, K. W. & Kang, T. J. Preparation and properties of electrically conducting textiles by in situ polymerization of poly(3,4-ethylenedioxythiophene). J. Appl. Polym. Sci. 97, 1326–1332 (2005).

    Article  CAS  Google Scholar 

  8. Carpi, F. & De Rossi, D. Electroactive polymer-based devices for e-textiles in biomedicine. IEEE Trans. Inform. Technol. Biomed. 9, 295–318 (2005).

    Article  Google Scholar 

  9. Maccioni, M., Orgiu, E., Cosseddu, P., Locci, S. & Bonfiglio, A. Towards the textile transistor: Assembly and characterization of an organic field effect transistor with a cylindrical geometry. Appl. Phys. Lett. 89, 143515 (2006).

    Article  Google Scholar 

  10. Johansson, T., Pettersson, L. A. A. & Inganas, O. Conductivity of de-doped poly(3,4-ethylenedioxythlophene). Synth. Met. 129, 269–274 (2002).

    Article  CAS  Google Scholar 

  11. Nilsson, D. et al. Bi-stable and dynamic current modulation in electrochemical organic transistors. Adv. Mater. 14, 51–54 (2002).

    Article  CAS  Google Scholar 

  12. Mabeck, J. T. et al. Microfluidic gating of an organic electrochemical transistor. Appl. Phys. Lett. 87, 013503 (2005).

    Article  Google Scholar 

  13. Nilsson, D., Robinson, N., Berggren, M. & Forchheimer, R. Electrochemical logic circuits. Adv. Mater. 17, 353 (2005).

    Article  CAS  Google Scholar 

  14. Andersson, P. et al. Active matrix displays based on all-organic electrochemical smart pixels printed on paper. Adv. Mater. 14, 1460 (2002).

    Article  CAS  Google Scholar 

  15. Daoud, W. A., Xin, J. H. & Szeto, Y. S. Polyethylenedioxythiophene coatings for humidity, temperature and strain sensing polyamide fibers. Sensors Actuators B 109, 329–333 (2005).

    Article  CAS  Google Scholar 

  16. Crispin, X. et al. The origin of the high conductivity of poly(3,4-ethylenedioxythiophene)- poly(styrenesulfonate) (PEDOT-PSS) plastic electrodes. Chem. Mater. 18, 4354–4360 (2006).

    Article  CAS  Google Scholar 

  17. Robinson, N. D., Svensson, P. O., Nilsson, D. & Berggren, M. On the current saturation observed in electrochemical polymer transistors. J. Electrochem. Soc. 153, H39–H44 (2006).

    Article  CAS  Google Scholar 

  18. Nyberg, T., Inganas, O. & Jerregard, H. Polymer hydrogel microelectrodes for neural communication. Biomed. Microdev. 4, 43–52 (2002).

    Article  CAS  Google Scholar 

  19. Herland, A. et al. Electroactive luminescent self-assembled bio-organic nanowires: Integration of semiconducting oligoelectrolytes within amyloidogenic proteins (vol 17, pg 1466, 2005). Adv. Mater. 17, 1703 (2005).

    Article  CAS  Google Scholar 

Download references

Acknowledgements

These investigations were financially supported by the Centre of Organic Electronics (COE) at Linköping University, Sweden, financed by the Strategic Research Foundation SSF. We thank W.-Y. Lin for electrical measurements on single WECTs and monofilaments, M. Asplund for discussions and K. Hamedi for graphic design. Textile fibres were kindly donated by Shakespeare, UK, and IFP Research, Mölndal, Sweden.

Author information

Authors and Affiliations

Authors

Contributions

M.H. carried out experiments. R.F. contributed to development of the logic design. O.I and M.H. wrote the manuscript. M.H., O.I. and R.F contributed to project planning.

Corresponding author

Correspondence to Olle Inganäs.

Ethics declarations

Competing interests

A patent application on this technology has been submitted by the authors.

Supplementary information

Supplementary Information

Supplementary figures 1S and 2S (PDF 414 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hamedi, M., Forchheimer, R. & Inganäs, O. Towards woven logic from organic electronic fibres. Nature Mater 6, 357–362 (2007). https://doi.org/10.1038/nmat1884

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/nmat1884

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing