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Nanoscale ferroelectric field-effect writing and reading using scanning tunnelling spectroscopy

Nature Materials volume 4, pages 378–382 (2005)Cite this article

Abstract

Control of the density of mobile charge carriers using electric fields is widely used in a variety of metal–insulator–semiconductor structures and is the governing principle behind the operation of field-effect transistors. Ferroelectric materials possessing a switchable and non-volatile polarization field can be used as insulating layers, revealing new opportunities for device applications1,2. Advances in material processing and in particular complex oxide thin-film growth mean that high-quality field-effect devices can be based on ferroelectric/metallic oxide heterostructures3,4,5,6,7,8,9,10,11. In addition, advances in local probe techniques such as atomic force microscopy allow them to be used in the imaging and study of small ferroelectric domain structures in bulk crystals12 and thin films13,14,15,16,17,18,19,20. Meanwhile, scanning tunnelling microscopy and spectroscopy have established themselves as powerful techniques for atomic manipulation and nanometre-resolution electron tunnelling spectroscopy21,22. Here, a scanning tunnelling microscope is used to investigate the ferroelectric field effect in all-perovskite heterostructures. Scanning tunnelling spectroscopy allows us to probe the local electronic properties of the polarized channel of a ferroelectric field-effect device as a function of the field orientation. This technique can be used to read and write ferroelectric field-induced regions with a size as low as 20 nm.

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Figure 1: SRTO/PZT/NSTO ferroelectric field-effect device.
Figure 2: STS characteristics of the SRTO channel showing semiconducting and ohmic behaviours as a function of the ferroelectric polarization state.
Figure 3: Ferroelectric domain writing/imaging/erasing.
Figure 4: Nanoscale ferroelectric domains.

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Acknowledgements

We thank Ch. Renner, J.-M. Triscone, T. Tybell and M. R. Eskildsen for valuable discussions, and A. P. Petrovic for critical reading of the manuscript. This work was supported by the Swiss National Science Foundation and through the National Centre of Competence in Research 'Materials with Novel Electronic Properties—MaNEP'.

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Authors and Affiliations

  1. Condensed Matter Physics Department, University of Geneva, Quai Ernest-Ansermet 24, Geneva, 4, CH-1211, Switzerland

    Olivier Kuffer, Ivan Maggio-Aprile & Øystein Fischer

  2. Also at: PHASIS Sàrl, 1228 Plan-les-Ouates, Geneva, Switzerland

    Olivier Kuffer

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  1. Olivier Kuffer
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Correspondence to Olivier Kuffer.

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Kuffer, O., Maggio-Aprile, I. & Fischer, Ø. Nanoscale ferroelectric field-effect writing and reading using scanning tunnelling spectroscopy. Nature Mater 4, 378–382 (2005). https://doi.org/10.1038/nmat1364

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