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A redox-stable efficient anode for solid-oxide fuel cells

Nature Materials volume 2, pages 320–323 (2003)Cite this article

Abstract

Solid-oxide fuel cells (SOFCs) promise high efficiencies in a range of fuels. Unlike lower temperature variants, carbon monoxide is a fuel rather than a poison, and so hydrocarbon fuels can be used directly, through internal reforming or even direct oxidation. This provides a key entry strategy for fuel-cell technology into the current energy economy. Present development is mainly based on the yttria-stabilized zirconia (YSZ) electrolyte1. The most commonly used anode materials are Ni/YSZ cermets, which display excellent catalytic properties for fuel oxidation and good current collection, but do exhibit disadvantages, such as low tolerance to sulphur2 and carbon deposition3 when using hydrocarbon fuels, and poor redox cycling causing volume instability. Here, we report a nickel-free SOFC anode, La0.75Sr0.25Cr0.5Mn0.5O3, with comparable electrochemical performance to Ni/YSZ cermets. The electrode polarization resistance approaches 0.2 Ω cm2 at 900 °C in 97% H2/3% H2O. Very good performance is achieved for methane oxidation without using excess steam. The anode is stable in both fuel and air conditions, and shows stable electrode performance in methane. Thus both redox stability and operation in low steam hydrocarbons have been demonstrated, overcoming two of the major limitations of the current generation of nickel zirconia cermet SOFC anodes.

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Figure 1
Figure 2: Electrode impedance of an optimized La0.75Sr0.25Cr0.5Mn0.5O3 anode:
Figure 3: Fuel-cell performance of a (La0.75Sr0.25)0.9Cr0.5Mn0.5O3 anode in different wet (3% H2O) atmospheres.

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Acknowledgements

We thank the Engineering and Physical Sciences Research Council (EPSRC) and the New Energy and Industrial Technology Development Organization (NEDO) (All Perovskite Solid Oxide Fuel Cell UK/Asian SOFC Project) for support.

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  1. School of Chemistry, University of St Andrews, Fife KY16 9ST, Scotland, UK

    Shanwen Tao & John T. S. Irvine

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  1. Shanwen Tao
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Correspondence to John T. S. Irvine.

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Tao, S., Irvine, J. A redox-stable efficient anode for solid-oxide fuel cells. Nature Mater 2, 320–323 (2003). https://doi.org/10.1038/nmat871

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