Article abstract


Nature Materials 2, 678 - 682 (2003)
Published online: 21 September 2003 | doi:10.1038/nmat978

There is a Corrigendum (December 2003) associated with this Article.

Subject Categories: Polymers | Semiconductors

Solution-processed ambipolar organic field-effect transistors and inverters

E. J. Meijer1,2, D. M. de Leeuw1, S. Setayesh1, E. van Veenendaal1, B. -H. Huisman1, P. W. M. Blom3, J. C. Hummelen3, U. Scherf4 & T. M. Klapwijk2


There is ample evidence that organic field-effect transistors have reached a stage where they can be industrialized, analogous to standard metal oxide semiconductor (MOS) transistors. Monocrystalline silicon technology is largely based on complementary MOS (CMOS) structures that use both n-type and p-type transistor channels. This complementary technology has enabled the construction of digital circuits, which operate with a high robustness, low power dissipation and a good noise margin. For the design of efficient organic integrated circuits, there is an urgent need for complementary technology, where both n-type and p-type transistor operation is realized in a single layer, while maintaining the attractiveness of easy solution processing. We demonstrate, by using solution-processed field-effect transistors, that hole transport and electron transport are both generic properties of organic semiconductors. This ambipolar transport is observed in polymers based on interpenetrating networks as well as in narrow bandgap organic semiconductors. We combine the organic ambipolar transistors into functional CMOS-like inverters.

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  1. Philips Research Laboratories, Professor Holstlaan 4, 5656 AA Eindhoven, The Netherlands
  2. Delft University of Technology, Faculty of Applied sciences, Department of NanoScience, Lorentzweg 1, 2628 CJ Delft, The Netherlands
  3. Materials Science Center, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands
  4. Bergische Universitat Wuppertal, Department of Chemistry, Gauss-strasse 20, D-42097 Wuppertal, Germany

Correspondence to: D. M. de Leeuw1 e-mail: dago.de.leeuw@philips.com

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