Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Brucite and carbonate assemblages from altered olivine-rich materials on Ceres

Abstract

The dwarf planet Ceres is the largest object in the asteroid belt, and is generally thought to be a differentiated body composed primarily of silicate materials and water ice1,2. Some remotely observed features, however, indicate that Ceres may instead have a composition more similar to that of the most common types of carbonaceous meteorite3,4,5,6,7. In particular, Ceres has been shown to have a distinct infrared absorption feature centred at a wavelength of 3.06 μm that is superimposed on a broader absorption from 2.8 to 3.7 μm (refs 58), which suggests the presence of OH- or H2O-bearing phases. The specific mineral composition of Ceres and its relationship to known meteorite mineral assemblages, however, remains uncertain. Here we show that the spectral features of Ceres can be attributed to the presence of the hydroxide brucite, magnesium carbonates and serpentines, a mineralogy consistent with the aqueous alteration of olivine-rich materials. We therefore suggest that the thermal and aqueous alteration history of Ceres is different from that recorded by carbonaceous meteorites, and that samples from Ceres are not represented in existing meteorite collections.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Linear mixing model results for the near-infrared reflectance spectrum of Ceres.
Figure 2: Linear mixing model results for the mid-infrared reflectance spectrum of Ceres.
Figure 3: Reflectance spectra of representative C1 and C2 carbonaceous chondrites.

Similar content being viewed by others

References

  1. McCord, T. & Sotin, C. Ceres: Evolution and current state. J. Geophys. Res. 110, E05009 (2005).

    Article  Google Scholar 

  2. Thomas, P.C. et al. Differentiation of the asteroid Ceres as revealed by its shape. Nature 437, 224–226 (2005).

    Article  Google Scholar 

  3. Johnson, T. V. & Fanale, F. Optical properties of carbonaceous chondrites and their relationship to asteroids. J. Geophys. Res. 75, 8507–8518 (1973).

    Article  Google Scholar 

  4. McCord, T. & Gaffey, M. J. Asteroids: Surface composition from reflectance spectroscopy. Science 186, 352–355 (1974).

    Article  Google Scholar 

  5. Lebofsky, L. A. Asteroid 1 Ceres: Evidence for water of hydration. Mon. Not. R. Astron. Soc. 182, 17–21 (1978).

    Article  Google Scholar 

  6. Feierberg, M., Lebofsky, L. & Larson, H. Spectroscopic evidence for aqueous alteration products on the surfaces of low-albedo asteroids. Geochim. Cosmo. Acta 45, 971–981 (1981).

    Article  Google Scholar 

  7. Rivkin, A., Volquardsen, E. & Clark, B. The surface composition of Ceres: Discovery of carbonates and iron-rich clays. Icarus 185, 563–567 (2007).

    Article  Google Scholar 

  8. Jones, T., Lebofsky, L., Lewis, J. & Marley, M. The composition and origin of the C, P, and D asteroids: Water as a tracer of thermal evolution in the outer belt. Icarus 88, 172–192 (1990).

    Article  Google Scholar 

  9. Gaffey, M., Burbine, T. & Binzel, R. Asteroid spectroscopy: Progress and perspectives. Meteoritics 28, 161–187 (1993).

    Article  Google Scholar 

  10. Lebofsky, L, Feierberg, M., Tokunaga, A., Larson, H. & Johnson, J. The 1.7–4.2 μm spectrum of asteroid 1 Ceres: Evidence for structural water in clay minerals. Icarus 48, 453–459 (1981).

    Article  Google Scholar 

  11. Fanale, F. P. & Salvail, J. R. The water regime of asteroid 1 Ceres. Icarus 82, 97–110 (1989).

    Article  Google Scholar 

  12. King, T., Clark, R., Calvin, W., Sherman, D. & Brown, R. Evidence for ammonium-bearing minerals on Ceres. Science 255, 1551–1553 (1992).

    Article  Google Scholar 

  13. Müller, W., Kurat, G. & Kracher, A. Chemical and crystallographic study of cronstedtite in the matrix of the Cochabamba (CM2) carbonaceous chondrite. Mineral. Petrol. 26, 293–304 (1979).

    Google Scholar 

  14. Mackinnon, I. & Buseck, P. New phyllosilicate types in a carbonaceous chondrite matrix. Nature 280, 219–220 (1979).

    Article  Google Scholar 

  15. Barber, D. Matrix phyllosilicates and associated minerals in C2M carbonaceous chondrites. Geochim. Cosmo. Acta 45, 945–970 (1981).

    Article  Google Scholar 

  16. Mara, R. T. & Sutherland, G. The infrared spectrum of brucite. J. Opt. Soc. Am. 43, 1100–1102 (1953).

    Article  Google Scholar 

  17. Tomeoka, K. & Buseck, P. Indicators of aqueous alteration in CM carbonaceous chondrites: Microtextures of a layered mineral containing Fe, S, O and Ni. Geochim. Cosmo. Acta 49, 2149–2163 (1985).

    Article  Google Scholar 

  18. Mackinnon, I. & Zolensky, M. Proposed structures for poorly characterized phases in C2M carbonaceous chondrite meteorites. Nature 309, 240–242 (1984).

    Article  Google Scholar 

  19. Moroz, L. V., Kozerenko, S. & Fadeev, V. The Reflectance Spectrum of Synthetic Tochilinite. 28th Lunar and Planetary Science Conf. 1288, LPI, Houston, TX (1997).

  20. Mara, R. T. The Infrared Spectrum of Crystalline Brucite (Mg(OH) 2). Thesis, Univ. Michigan (1954).

  21. Frost, R. & Kloprogge, J. Infrared emission spectroscopic study of brucite. Spectro. Acta 55, 2195–2205 (1999).

    Article  Google Scholar 

  22. Cohen, M., Witteborn, F., Roush, T., Bregman, J. & Wooden, D. Spectral irradiance calibration in the infrared. VIII. 5–14 μm spectroscopy of the asteroids Ceres, Vesta, and Pallas. Astron. J. 115, 1671–1679 (1998).

    Article  Google Scholar 

  23. Milliken, R. E. & Mustard, J. Estimating the water content of hydrated minerals using reflectance spectroscopy I. Effects of darkening agents and low-albedo materials. Icarus 189, 550–573 (2007).

    Article  Google Scholar 

  24. Britt, D. & Pieters, C. Darkening in black and gas-rich ordinary chondrites: The spectral effects of opaque morphology and distribution. Geochim. Cosmo. Acta 58, 3905–3919 (1994).

    Article  Google Scholar 

  25. Clark, R. M. Spectral properties of mixtures of montmorillonite and dark carbon grains: Implications for remote sensing minerals containing chemically and physically adsorbed water. J. Geophys. Res. 88, 10635–10644 (1983).

    Article  Google Scholar 

  26. Grimm, R. E. & McSween, H. Water and the thermal evolution of carbonaceous chondrite parent bodies. Icarus 82, 244 (1989).

    Article  Google Scholar 

  27. Nesbitt, H. W. & Bricker, O. Low temperature alteration processes affecting ultramafic bodies. Geochim. Cosmo. Acta 42, 403–409 (1978).

    Article  Google Scholar 

  28. Peng, Y. et al. An experimental study on the hydrothermal preparation of tochilinite nanotubes and tochilinite-serpentine-intergrowth nanotubes from metal particulates. Geochim. Cosmo. Acta 71, 2858–2875 (2007).

    Article  Google Scholar 

  29. Benedix, G., Leshin, L., Farquhar, J., Jackson, T. & Thiemens, M. Carbonates in CM2 chondrites: Constraints on alteration conditions from oxygen isotopic compositions and petrographic observations. Geochim. Cosmo. Acta 67, 1577–1588 (2003).

    Article  Google Scholar 

  30. Rayman, M., Fraschetti, T., Raymond, C. & Russell, C. Dawn: A mission in development for exploration of main belt asteroids Vesta and Ceres. Acta Astronaut. 58, 605–616 (2006).

    Article  Google Scholar 

Download references

Acknowledgements

This research was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with NASA. We also acknowledge support from RELAB at Brown University, the NASA Planetary Astronomy Program and the Infrared Telescope Facility, which is operated by the University of Hawaii under Cooperative Agreement no. NCC 5-538 with the NASA Planetary Astronomy Program.

Author information

Authors and Affiliations

Authors

Contributions

R.E.M. was responsible for writing most of the text and the spectral modelling. A.S.R. contributed to the text, acquired and provided the near-infrared spectrum of Ceres and assisted with interpretation of the results.

Corresponding author

Correspondence to Ralph E. Milliken.

Supplementary information

Supplementary Information

Supplementary Information (PDF 358 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Milliken, R., Rivkin, A. Brucite and carbonate assemblages from altered olivine-rich materials on Ceres. Nature Geosci 2, 258–261 (2009). https://doi.org/10.1038/ngeo478

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/ngeo478

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing