Scheme 1 - The pikromycin biosynthetic pathway in S. venezuelae ATCC 15439.

From the following article

Structural and mechanistic insights into polyketide macrolactonization from polyketide-based affinity labels

John W Giraldes, David L Akey, Jeffrey D Kittendorf, David H Sherman, Janet L Smith & Robert A Fecik

Nature Chemical Biology 2, 531 - 536 (2006) Published online: 10 September 2006

doi:10.1038/nchembio822

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Numbers on structures denote atom positions referred to in the text.

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