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Nature Chemistry (6 February 2009) | doi:10.1038/nchem.127

Interlocked molecules: Mix and match

Anne Pichon

Catenanes — molecules comprising interlocked rings not covalently bonded to each other — initially attracted attention for their unusual structures, but are now being used in molecular electronic devices. Their synthesis, which has traditionally required pre-organization of the precursors via non-covalent interactions, has often been achieved by interlocking a ring containing |[pi]|-donor groups with one containing |[pi]|-acceptor groups.