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Molecular magnetism

Uranium memory

A diuranium compound featuring an arene bridge shows single-molecule-magnet behaviour, which could arise from a mechanism different from the traditional 'super-exchange' spin coupling.

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Figure 1: An arene-bridged diuranium complex exhibits SMM behaviour.

References

  1. Gatteschi, D., Sessoli, R. & Villain, J. Molecular Nanomagnets (Oxford Univ. Press, 2006).

    Book  Google Scholar 

  2. Mills, D. P. et al. Nature Chem. 3, 454–460 10.1038/nchem.1028 (2011).

    Article  CAS  Google Scholar 

  3. Winpenny, R. E. P. (ed.) Single-Molecule Magnets and Related Phenomena (Structure and Bonding) (Springer, 2006).

    Book  Google Scholar 

  4. Rinehart, J. D. & Long, J. R., J. Am. Chem. Soc. 131, 12558–12559 (2009).

    Article  CAS  Google Scholar 

  5. Magnani, N. et al. Angew. Chem. Int. Ed. 50, 1696–1698 (2011).

    Article  CAS  Google Scholar 

  6. Rosen, R. K., Andersen, R. A. & Edelstein, N. M. J. Am. Chem. Soc. 112, 4588–4590 (1990).

    Article  CAS  Google Scholar 

  7. Nocton, G., Horeglad, P., Pecaut, J. & Mazzanti, M. J. Am. Chem. Soc. 130, 16633–16645 (2008).

    Article  CAS  Google Scholar 

  8. Mougel, V., Horeglad, P., Nocton, G., Pecaut, J. & Mazzanti, M. Angew. Chem. Int. Ed. 48, 8477–8480 (2009).

    Article  CAS  Google Scholar 

  9. Spencer, L. P. et al. Angew. Chem. Int. Ed. 48, 3795–3798 (2009).

    Article  CAS  Google Scholar 

  10. Rinehart, J. D., Harris, T. D., Kozimor, S. A., Bartlett, B. M. & Long, J. R. Inorg. Chem. 48, 3382–3395 (2009).

    Article  CAS  Google Scholar 

  11. Diaconescu, P. L., Arnold, P. L., Baker, T. A., Mindiola, D. J. & Cummins, C. C.J. Am. Chem. Soc. 122, 6108–6109 (2000).

    Article  CAS  Google Scholar 

  12. Evans, W. J., Kozimor, S. A., Ziller, J. W. & Kaltsoyannis, N. J. Am. Chem. Soc. 126, 14533–14547 (2004).

    Article  CAS  Google Scholar 

  13. Bechlars, B. et al. Nature Chem. 2, 362–368 (2010).

    Article  CAS  Google Scholar 

  14. Lin, P. H. et al. Angew. Chem. Int. Ed. 48, 9489–9492 (2009).

    Article  CAS  Google Scholar 

Download references

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Correspondence to Marinella Mazzanti.

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Mazzanti, M. Uranium memory. Nature Chem 3, 426–427 (2011). https://doi.org/10.1038/nchem.1057

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