Many different kinds of switchable molecules and materials are based on transition metal ions, but similar properties are also possible in organic materials. Now, two separate studies reveal new insights into the ability of organic radicals to associate reversibly and cooperatively in the solid state, and in so doing create bistable, hysteretic materials.
This is a preview of subscription content, access via your institution
Relevant articles
Open Access articles citing this article.
-
Achieving large thermal hysteresis in an anthracene-based manganese(II) complex via photo-induced electron transfer
Nature Communications Open Access 12 May 2022
-
The Non-innocent Phenalenyl Unit: An Electronic Nest to Modulate the Catalytic Activity in Hydroamination Reaction
Scientific Reports Open Access 02 October 2013
Access options
Subscribe to this journal
Receive 12 print issues and online access
$259.00 per year
only $21.58 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
References
Raymo, F. M. Adv. Mater. 14, 401–414 (2002).
Gütlich, P., Hauser, A. & Spiering, H. Angew. Chem. Int. Ed. 33, 2024–2054 (1994).
Sato, O., Tao, J. & Zhang, Y. Z. Angew. Chem. Int. Ed. 46, 2152–2187 (2007).
Pal, S. K. et al. J. Am. Chem. Soc. 132, 17258–17264 (2010).
Lekin, K. et al. J. Am. Chem. Soc. 132, 16212–16224 (2010).
Itkis, M. E. et al. Science 296, 1443–1445 (2002).
Haddon, R. C. et al. J. Am. Chem. Soc. 130, 13683–13690 (2008).
Barclay, T. M. et al. J. Am. Chem. Soc. 120, 352–360 (1998).
Fujita, W. & Awaga, K. Science 286, 261–262 (1999).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hicks, R. A new spin on bistability. Nature Chem 3, 189–191 (2011). https://doi.org/10.1038/nchem.997
Published:
Issue Date:
DOI: https://doi.org/10.1038/nchem.997
This article is cited by
-
Achieving large thermal hysteresis in an anthracene-based manganese(II) complex via photo-induced electron transfer
Nature Communications (2022)
-
Switching the magnetic hysteresis of an [Feii–NC–Wv]-based coordination polymer by photoinduced reversible spin crossover
Nature Chemistry (2021)
-
Dynamic molecular crystals with switchable physical properties
Nature Chemistry (2016)
-
The key role of vibrational entropy in the phase transitions of dithiazolyl-based bistable magnetic materials
Nature Communications (2014)
-
The Non-innocent Phenalenyl Unit: An Electronic Nest to Modulate the Catalytic Activity in Hydroamination Reaction
Scientific Reports (2013)