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Metal–organic frameworks

Entering the recognition domain

The host–guest properties of metal–organic frameworks have usually relied on molecular separation by the pore aperture or non-specific binding with the pore walls. Incorporating supramolecular recognition units into the frameworks has now enabled the docking of a specific guest.

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Figure 1: Illustration of the way molecular recognition sites are incorporated into MOFs.

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Kim, K. Entering the recognition domain. Nature Chem 1, 603–604 (2009). https://doi.org/10.1038/nchem.419

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