Nature © Macmillan Publishers Ltd. X-ray astronomy: Polarimetry sees the lightEthane is in the chemistry textbooks as a molecule that can switch between unstable and stable conformations by an internal rotation, with steric repulsion usually invoked to explain the preferred 'staggered' arrangement of its two methyl groups. A new look at the ethane molecule reveals a rather different picture, in which ethane�s structural state is determined principally by hyperconjugation. This is a quantum mechanical effect that involves charge delocalization due to transfer of electrons from occupied to unoccupied orbitals.
| ||
|
|