Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Electron attraction mediated by Coulomb repulsion

Abstract

One of the defining properties of electrons is their mutual Coulomb repulsion. However, in solids this basic property may change; for example, in superconductors, the coupling of electrons to lattice vibrations makes the electrons attract one another, leading to the formation of bound pairs. Fifty years ago it was proposed1 that electrons can be made attractive even when all of the degrees of freedom in the solid are electronic, by exploiting their repulsion from other electrons. This attraction mechanism, termed ‘excitonic’, promised to achieve stronger and more exotic superconductivity2,3,4,5,6. Yet, despite an extensive search7, experimental evidence for excitonic attraction has yet to be found. Here we demonstrate this attraction by constructing, from the bottom up, the fundamental building block8 of the excitonic mechanism. Our experiments are based on quantum devices made from pristine carbon nanotubes, combined with cryogenic precision manipulation. Using this platform, we demonstrate that two electrons can be made to attract each other using an independent electronic system as the ‘glue’ that mediates attraction. Owing to its tunability, our system offers insights into the underlying physics, such as the dependence of the emergent attraction on the underlying repulsion, and the origin of the pairing energy. We also demonstrate transport signatures of excitonic pairing. This experimental demonstration of excitonic pairing paves the way for the design of exotic states of matter.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Model system and experimental realization of its fundamental building block.
Figure 2: From repulsive to attractive electrons.
Figure 3: Dependence of pairing energy on the polarizer detuning and the origin of the pair binding energy.
Figure 4: Transport measurements.

Similar content being viewed by others

References

  1. Little, W. A. Possibility of synthesizing an organic superconductor. Phys. Rev. 134, A1416–A1424 (1964)

    Article  ADS  Google Scholar 

  2. Ginzburg, V. L. Concerning surface superconductivity. Sov. Phys. JETP 20, 1549–1550 (1964)

    Google Scholar 

  3. Allender, D. & Bardeen, J. Model for an exciton mechanism of superconductivity. Phys. Rev. B 7, 1020–1029 (1973)

    Article  CAS  ADS  Google Scholar 

  4. Ginzburg, V. L. High-temperature superconductivity—dream or reality? Sov. Phys. Usp. 19, 174–179 (1976)

    Article  ADS  Google Scholar 

  5. Hirsch, J. E. & Scalapino, D. J. Excitonic mechanism for superconductivity in a quasi-one-dimensional system. Phys. Rev. B 32, 117–134 (1985)

    Article  CAS  ADS  Google Scholar 

  6. Micnas, R., Ranninger, J. & Robaszkiewicz, S. Superconductivity in narrow-band systems with local nonretarded attractive interactions. Rev. Mod. Phys. 62, 113–171 (1990)

    Article  CAS  ADS  Google Scholar 

  7. Jérome, D. in The Physics of Organic Superconductors and Conductors (ed. Lebed, A. ) 3–16 (Springer, 2008)

  8. Raikh, M. E., Glazman, L. I. & Zhukov, L. E. Two-electron state in a disordered 2D island: pairing caused by the coulomb repulsion. Phys. Rev. Lett. 77, 1354–1357 (1996)

    Article  ADS  Google Scholar 

  9. Bardeen, J., Cooper, L. & Schrieffer, J. Microscopic theory of superconductivity. Phys. Rev. 106, 162–164 (1957)

    Article  CAS  ADS  MathSciNet  Google Scholar 

  10. Hirsch, J. E. & Scalapino, D. J. Double-valence-fluctuating molecules and superconductivity. Phys. Rev. B 32, 5639–5643 (1985)

    Article  CAS  ADS  Google Scholar 

  11. Varma, C. Missing valence states, diamagnetic insulators, and superconductors. Phys. Rev. Lett. 61, 2713–2716 (1988)

    Article  CAS  ADS  Google Scholar 

  12. Matsushita, Y., Bluhm, H., Geballe, T. H. & Fisher, I. R. Evidence for charge Kondo effect in superconducting Tl-doped PbTe. Phys. Rev. Lett. 94, 157002 (2005)

    Article  CAS  ADS  Google Scholar 

  13. Butler, M. R., Movaghar, B., Marks, T. J. & Ratner, M. A. Electron pairing in designer materials: a novel strategy for a negative effective Hubbard U. Nano Lett. 15, 1597–1602 (2015)

    Article  CAS  ADS  Google Scholar 

  14. Oganesyan, V., Kivelson, S., Geballe, T. & Moyzhes, B. Josephson tunneling spectroscopy of negative-U centers. Phys. Rev. B 65, 172504 (2002)

    Article  ADS  Google Scholar 

  15. Hirsch, J. E., Tang, S., Loh, E. Jr & Scalapino, D. J. Pairing interaction in two-dimensional CuO2 . Phys. Rev. Lett. 60, 1668–1671 (1988)

    Article  CAS  ADS  Google Scholar 

  16. Ge, J. et al. Superconductivity above 100 K in single-layer FeSe films on doped SrTiO3 . Nat. Mater. 14, 285–289 (2015)

    Article  CAS  ADS  Google Scholar 

  17. Richter, C. et al. Interface superconductor with gap behaviour like a high-temperature superconductor. Nature 502, 528–531 (2013)

    Article  CAS  ADS  Google Scholar 

  18. Cheng, G. et al. Electron pairing without superconductivity. Nature 521, 196–199 (2015)

    Article  CAS  ADS  Google Scholar 

  19. Firstenberg, O. et al. Attractive photons in a quantum nonlinear medium. Nature 502, 71–75 (2013)

    Article  CAS  ADS  Google Scholar 

  20. Waissman, J. et al. Realization of pristine and locally tunable one-dimensional electron systems in carbon nanotubes. Nat. Nanotechnol. 8, 569–574 (2013)

    Article  CAS  ADS  Google Scholar 

  21. Averin, D. V. & Bruder, C. Variable electrostatic transformer: controllable coupling of two charge qubits. Phys. Rev. Lett. 91, 057003 (2003)

    Article  CAS  ADS  Google Scholar 

  22. Lobos, A. M., Iucci, A., Müller, M. & Giamarchi, T. Dissipation-driven phase transitions in superconducting wires. Phys. Rev. B 80, 214515 (2009)

    Article  ADS  Google Scholar 

  23. Goldstein, M., Berkovits, R. & Gefen, Y. Population switching and charge sensing in quantum dots: a case for a quantum phase transition. Phys. Rev. Lett. 104, 226805 (2010)

    Article  ADS  Google Scholar 

  24. Yoo, G., Park, J., Lee, S.-S. B. & Sim, H.-S. Anisotropic charge Kondo effect in a triple quantum dot. Phys. Rev. Lett. 113, 236601 (2014)

    Article  ADS  Google Scholar 

  25. Medford, J. et al. Quantum-dot-based resonant exchange qubit. Phys. Rev. Lett. 111, 050501 (2013)

    Article  CAS  ADS  Google Scholar 

  26. Braakman, F., Barthelemy, P., Reichl, C., Wegscheider, W. & Vandersypen, L. M. K. Long-distance coherent coupling in a quantum dot array. Nat. Nanotechnol. 8, 432–437 (2013)

    Article  CAS  ADS  Google Scholar 

  27. Seo, M. et al. Charge frustration in a triangular triple quantum dot. Phys. Rev. Lett. 110, 046803 (2013)

    Article  CAS  ADS  Google Scholar 

  28. Delbecq, M. R. et al. Full control of quadruple quantum dot circuit charge states in the single electron regime. Appl. Phys. Lett. 104, 183111 (2014)

    Article  ADS  Google Scholar 

  29. Fölsch, S., Martínez-Blanco, J., Yang, J., Kanisawa, K. & Erwin, S. C. Quantum dots with single-atom precision. Nat. Nanotechnol. 9, 505–508 (2014)

    Article  ADS  Google Scholar 

Download references

Acknowledgements

We thank E. Altman, E. Berg, Y. Gefen, M. Goldstein, U. Leonhardt, G. Refael and A. Yacoby for discussions and D. Mahalu for the e-beam writing. K.K. acknowledges support from the Carlsberg Foundation. Y.O. acknowledges support by Minerva, BSF and ERC Adg grant (FP7/2007-2013 340210). F.v.O. acknowledges support through SPP 1459 and SFB 658. S.I. acknowledges financial support by the ERC Cog grant (See-1D-Qmatter, No. 647413).

Reviewer Information Nature thanks R. Egger, T. Kontos and E. Scheer for their contribution to the peer review of this work.

Author information

Authors and Affiliations

Authors

Contributions

A.H., A.B., I.S. and S.I. performed the experiments, analysed the data, contributed to its theoretical interpretation and wrote the paper. I.S. built the scanning probe microscope. I.K. built the custom measurement instrumentation for the experiment. J.W. designed and fabricated the devices. K.K., Y.O. and F.v.O. developed the theoretical model. K.K. performed the theoretical simulations.

Corresponding author

Correspondence to S. Ilani.

Ethics declarations

Competing interests

The authors declare no competing financial interests.

Supplementary information

Supplementary Information

This file contains Supplementary Text and Data, which includes Supplementary Methods, Supplementary Figures 1-10, a Supplementary Discussion and additional references. (PDF 2798 kb)

PowerPoint slides

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hamo, A., Benyamini, A., Shapir, I. et al. Electron attraction mediated by Coulomb repulsion. Nature 535, 395–400 (2016). https://doi.org/10.1038/nature18639

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/nature18639

This article is cited by

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing