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Evidence for a terminal Pt(iv)-oxo complex exhibiting diverse reactivity

Elena Poverenov, Irena Efremenko, Anatoly I. Frenkel, Yehoshoa Ben-David, Linda J. W. Shimon, Gregory Leitus, Leonid Konstantinovski, Jan M. L. Martin & David Milstein

Nature 455, 1093-1096(23 October 2008)

doi:10.1038/nature07356

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Figure 1 - Unfortunately we are unable to provide accessible alternative text for this. If you require assistance to access this image, or to obtain a text description, please contact npg@nature.com

Figure 1

Preparation and DFT structure of complex 2.

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Figure 2

XANES spectra of complexes and Fourier transform magnitudes of EXAFS data.

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Figure 3

Reactivity of complex 2.

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Figure 4

ORTEP views of molecules of 3 and 4 with the thermal ellipsoids at 50% probability.

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